The first aminimide synthesis from benzoyl azide and pyridine

Benny Capuano; Ian Travers Crosby; Edward John Lloyd; Juliette E Neve

The first aminimide synthesis from benzoyl azide and pyridine

Benny Capuano
, Ian Travers Crosby
, Edward John Lloyd
, Juliette E Neve

Medicinal Chemistry

Research output: Contribution to journal › Article › Research › peer-review

6 Citations (Scopus)

Abstract

Irradiation of benzoyl azide 1 at 254 nm in the presence of some amines produces aminimides: in the presence of pyridine the aminimide 13 can be isolated in 41 yield; in the presence of N,N-dimethylaniline a CH insertion product 7 is obtained via an intermediate aminimide 12. This is the first reported synthesis of aminimides from a benzoyl azide.

Original language	English
Pages (from-to)	214 - 217
Number of pages	4
Journal	Australian Journal of Chemistry
Volume	60
Issue number	3
Publication status	Published - 2007

Cite this

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title = "The first aminimide synthesis from benzoyl azide and pyridine",

abstract = "Irradiation of benzoyl azide 1 at 254 nm in the presence of some amines produces aminimides: in the presence of pyridine the aminimide 13 can be isolated in 41 yield; in the presence of N,N-dimethylaniline a CH insertion product 7 is obtained via an intermediate aminimide 12. This is the first reported synthesis of aminimides from a benzoyl azide.",

author = "Benny Capuano and Crosby, \{Ian Travers\} and Lloyd, \{Edward John\} and Neve, \{Juliette E\}",

year = "2007",

language = "English",

volume = "60",

pages = "214 -- 217",

journal = "Australian Journal of Chemistry",

issn = "1445-0038",

publisher = "CSIRO Publishing",

number = "3",

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TY - JOUR

T1 - The first aminimide synthesis from benzoyl azide and pyridine

AU - Capuano, Benny

AU - Crosby, Ian Travers

AU - Lloyd, Edward John

AU - Neve, Juliette E

PY - 2007

Y1 - 2007

N2 - Irradiation of benzoyl azide 1 at 254 nm in the presence of some amines produces aminimides: in the presence of pyridine the aminimide 13 can be isolated in 41 yield; in the presence of N,N-dimethylaniline a CH insertion product 7 is obtained via an intermediate aminimide 12. This is the first reported synthesis of aminimides from a benzoyl azide.

AB - Irradiation of benzoyl azide 1 at 254 nm in the presence of some amines produces aminimides: in the presence of pyridine the aminimide 13 can be isolated in 41 yield; in the presence of N,N-dimethylaniline a CH insertion product 7 is obtained via an intermediate aminimide 12. This is the first reported synthesis of aminimides from a benzoyl azide.

UR - http://<Go to ISI>://000245341700012

M3 - Article

SN - 1445-0038

VL - 60

SP - 214

EP - 217

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 3

ER -

The first aminimide synthesis from benzoyl azide and pyridine

Abstract

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