The first 4d/4f single-molecule magnet containing a {RuIII2DyIII2} core

Stuart K Langley; Daniel Patrick Wielechowski; Veacheslav Vieru; Nicholas Frederick Chilton; Boujemaa Moubaraki; Liviu Chibotaru; Keith Spencer Murray

doi:10.1039/c4cc08811e

The first 4d/4f single-molecule magnet containing a {RuIII2DyIII2} core

Stuart K Langley, Daniel Patrick Wielechowski, Veacheslav Vieru, Nicholas Frederick Chilton, Boujemaa Moubaraki, Liviu Chibotaru, Keith Spencer Murray

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

16 Citations (Scopus)

Abstract

We report the synthesis, structure and magnetic properties of the first 4d-4f single-molecule magnet. The complex [RuIII 2DyIII 2(OMe)2(O2CPh)4(mdea)2(NO3)2] displays a butterfly type core, with an anisotropy barrier of 10.7 cm-1. Ab initio and DFT calculations provide insight into the observed magnetic behaviour.

Original language	English
Pages (from-to)	2044 - 2047
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	11
DOIs	https://doi.org/10.1039/c4cc08811e
Publication status	Published - 2015

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10.1039/c4cc08811e

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Cite this

Langley, S. K., Wielechowski, D. P., Vieru, V., Chilton, N. F., Moubaraki, B., Chibotaru, L., & Murray, K. S. (2015). The first 4d/4f single-molecule magnet containing a {RuIII2DyIII2} core. Chemical Communications, 51(11), 2044 - 2047. https://doi.org/10.1039/c4cc08811e

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title = "The first 4d/4f single-molecule magnet containing a {RuIII2DyIII2} core",

abstract = "We report the synthesis, structure and magnetic properties of the first 4d-4f single-molecule magnet. The complex [RuIII 2DyIII 2(OMe)2(O2CPh)4(mdea)2(NO3)2] displays a butterfly type core, with an anisotropy barrier of 10.7 cm-1. Ab initio and DFT calculations provide insight into the observed magnetic behaviour.",

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doi = "10.1039/c4cc08811e",

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The first 4d/4f single-molecule magnet containing a {RuIII2DyIII2} core. / Langley, Stuart K; Wielechowski, Daniel Patrick; Vieru, Veacheslav; Chilton, Nicholas Frederick; Moubaraki, Boujemaa; Chibotaru, Liviu; Murray, Keith Spencer.

In: Chemical Communications, Vol. 51, No. 11, 2015, p. 2044 - 2047.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - The first 4d/4f single-molecule magnet containing a {RuIII2DyIII2} core

AU - Langley, Stuart K

AU - Wielechowski, Daniel Patrick

AU - Vieru, Veacheslav

AU - Chilton, Nicholas Frederick

AU - Moubaraki, Boujemaa

AU - Chibotaru, Liviu

AU - Murray, Keith Spencer

PY - 2015

Y1 - 2015

N2 - We report the synthesis, structure and magnetic properties of the first 4d-4f single-molecule magnet. The complex [RuIII 2DyIII 2(OMe)2(O2CPh)4(mdea)2(NO3)2] displays a butterfly type core, with an anisotropy barrier of 10.7 cm-1. Ab initio and DFT calculations provide insight into the observed magnetic behaviour.

AB - We report the synthesis, structure and magnetic properties of the first 4d-4f single-molecule magnet. The complex [RuIII 2DyIII 2(OMe)2(O2CPh)4(mdea)2(NO3)2] displays a butterfly type core, with an anisotropy barrier of 10.7 cm-1. Ab initio and DFT calculations provide insight into the observed magnetic behaviour.

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U2 - 10.1039/c4cc08811e

DO - 10.1039/c4cc08811e

M3 - Article

VL - 51

SP - 2044

EP - 2047

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

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