The chemistry of organothallium compounds. Part III. Far-infrared spectra of halogenobis(pentafluorophenyl)thallium(III) compounds

G. B. Deacon; J. H S Green; W. Kynaston

doi:10.1039/J19670000158

The chemistry of organothallium compounds. Part III. Far-infrared spectra of halogenobis(pentafluorophenyl)thallium(III) compounds

G. B. Deacon, J. H S Green, W. Kynaston

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

19 Citations (Scopus)

Abstract

The far-infrared spectra (400-50 cm. ^-1) of halogenobis(pentafluorophenyl)thallium(III) compounds, (R _F) ₂TIX (R _F = C ₆F ₅; X = F, Cl, or Br), of the complexes (R _F) ₂Ph ₃POTIX (X = Cl or Br), and of bispentafluorophenyl-mercury have been recorded. Assignments are suggested for the thallium-halogen frequencies, and the structures of the (R _F) ₂TIX compounds are discussed.

Original language	English
Pages (from-to)	158-161
Number of pages	4
Journal	Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry
DOIs	https://doi.org/10.1039/J19670000158
Publication status	Published - 1 Dec 1967

Access to Document

10.1039/J19670000158

Link to publication in Scopus

Cite this

@article{6022f7f55c204f94b6172bd15140133e,

title = "The chemistry of organothallium compounds. Part III. Far-infrared spectra of halogenobis(pentafluorophenyl)thallium(III) compounds",

abstract = "The far-infrared spectra (400-50 cm. -1) of halogenobis(pentafluorophenyl)thallium(III) compounds, (R F) 2TIX (R F = C 6F 5; X = F, Cl, or Br), of the complexes (R F) 2Ph 3POTIX (X = Cl or Br), and of bispentafluorophenyl-mercury have been recorded. Assignments are suggested for the thallium-halogen frequencies, and the structures of the (R F) 2TIX compounds are discussed.",

author = "Deacon, {G. B.} and Green, {J. H S} and W. Kynaston",

year = "1967",

month = dec,

day = "1",

doi = "10.1039/J19670000158",

language = "English",

pages = "158--161",

journal = "Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry",

issn = "0022-4944",

publisher = "The Royal Society of Chemistry",

}

TY - JOUR

T1 - The chemistry of organothallium compounds. Part III. Far-infrared spectra of halogenobis(pentafluorophenyl)thallium(III) compounds

AU - Deacon, G. B.

AU - Green, J. H S

AU - Kynaston, W.

PY - 1967/12/1

Y1 - 1967/12/1

N2 - The far-infrared spectra (400-50 cm. -1) of halogenobis(pentafluorophenyl)thallium(III) compounds, (R F) 2TIX (R F = C 6F 5; X = F, Cl, or Br), of the complexes (R F) 2Ph 3POTIX (X = Cl or Br), and of bispentafluorophenyl-mercury have been recorded. Assignments are suggested for the thallium-halogen frequencies, and the structures of the (R F) 2TIX compounds are discussed.

AB - The far-infrared spectra (400-50 cm. -1) of halogenobis(pentafluorophenyl)thallium(III) compounds, (R F) 2TIX (R F = C 6F 5; X = F, Cl, or Br), of the complexes (R F) 2Ph 3POTIX (X = Cl or Br), and of bispentafluorophenyl-mercury have been recorded. Assignments are suggested for the thallium-halogen frequencies, and the structures of the (R F) 2TIX compounds are discussed.

UR - http://www.scopus.com/inward/record.url?scp=37049139104&partnerID=8YFLogxK

U2 - 10.1039/J19670000158

DO - 10.1039/J19670000158

M3 - Article

AN - SCOPUS:37049139104

SP - 158

EP - 161

JO - Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry

JF - Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry

SN - 0022-4944

ER -