The chemistry of organothallium compounds. Part III. Far-infrared spectra of halogenobis(pentafluorophenyl)thallium(III) compounds

G. B. Deacon, J. H S Green, W. Kynaston

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Abstract

The far-infrared spectra (400-50 cm. -1) of halogenobis(pentafluorophenyl)thallium(III) compounds, (R F) 2TIX (R F = C 6F 5; X = F, Cl, or Br), of the complexes (R F) 2Ph 3POTIX (X = Cl or Br), and of bispentafluorophenyl-mercury have been recorded. Assignments are suggested for the thallium-halogen frequencies, and the structures of the (R F) 2TIX compounds are discussed.

Original languageEnglish
Pages (from-to)158-161
Number of pages4
JournalJournal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry
DOIs
Publication statusPublished - 1 Dec 1967

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