The chemistry of organothallium compounds. Part III. Far-infrared spectra of halogenobis(pentafluorophenyl)thallium(III) compounds

G. B. Deacon, J. H S Green, W. Kynaston

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Abstract

The far-infrared spectra (400-50 cm. -1) of halogenobis(pentafluorophenyl)thallium(III) compounds, (R F) 2TIX (R F = C 6F 5; X = F, Cl, or Br), of the complexes (R F) 2Ph 3POTIX (X = Cl or Br), and of bispentafluorophenyl-mercury have been recorded. Assignments are suggested for the thallium-halogen frequencies, and the structures of the (R F) 2TIX compounds are discussed.

Original languageEnglish
Pages (from-to)158-161
Number of pages4
JournalJournal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry
DOIs
Publication statusPublished - 1 Dec 1967

Cite this

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title = "The chemistry of organothallium compounds. Part III. Far-infrared spectra of halogenobis(pentafluorophenyl)thallium(III) compounds",
abstract = "The far-infrared spectra (400-50 cm. -1) of halogenobis(pentafluorophenyl)thallium(III) compounds, (R F) 2TIX (R F = C 6F 5; X = F, Cl, or Br), of the complexes (R F) 2Ph 3POTIX (X = Cl or Br), and of bispentafluorophenyl-mercury have been recorded. Assignments are suggested for the thallium-halogen frequencies, and the structures of the (R F) 2TIX compounds are discussed.",
author = "Deacon, {G. B.} and Green, {J. H S} and W. Kynaston",
year = "1967",
month = "12",
day = "1",
doi = "10.1039/J19670000158",
language = "English",
pages = "158--161",
journal = "Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry",
issn = "0022-4944",
publisher = "Royal Society of Chemistry (RSC)",

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TY - JOUR

T1 - The chemistry of organothallium compounds. Part III. Far-infrared spectra of halogenobis(pentafluorophenyl)thallium(III) compounds

AU - Deacon, G. B.

AU - Green, J. H S

AU - Kynaston, W.

PY - 1967/12/1

Y1 - 1967/12/1

N2 - The far-infrared spectra (400-50 cm. -1) of halogenobis(pentafluorophenyl)thallium(III) compounds, (R F) 2TIX (R F = C 6F 5; X = F, Cl, or Br), of the complexes (R F) 2Ph 3POTIX (X = Cl or Br), and of bispentafluorophenyl-mercury have been recorded. Assignments are suggested for the thallium-halogen frequencies, and the structures of the (R F) 2TIX compounds are discussed.

AB - The far-infrared spectra (400-50 cm. -1) of halogenobis(pentafluorophenyl)thallium(III) compounds, (R F) 2TIX (R F = C 6F 5; X = F, Cl, or Br), of the complexes (R F) 2Ph 3POTIX (X = Cl or Br), and of bispentafluorophenyl-mercury have been recorded. Assignments are suggested for the thallium-halogen frequencies, and the structures of the (R F) 2TIX compounds are discussed.

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U2 - 10.1039/J19670000158

DO - 10.1039/J19670000158

M3 - Article

SP - 158

EP - 161

JO - Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry

JF - Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry

SN - 0022-4944

ER -