Tetragonal micro/nanotwins in 0.91Pb (Zn1/3Nb 2/3)O3 - 0.09 PbTiO3 revealed by reciprocal space mapping

W. S. Chang, L. C. Lim, P. Yang, H. Miao, C. S. Tu, Qiming Chen, A. K. Soh

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Abstract

Reciprocal space mapping (RSM) of the relaxor ferroelectric 0.91Pb(Zn 1/3Nb2/3)O3-0.09 PbTiO3 PZN-9%PT) single crystals has been performed by using high-resolution synchrotron x-ray diffraction as a function of temperature. The PZN-9%PT crystal consists of tetragonal micro/nanotwin domains and undergoes a sequence of rhombohedral+tetragonal→tetragonal→cubic phase transformation upon heating. The rhombohedral-to-tetragonal temperature occurs at ≃70 °C. The observed RSM patterns can be explained by the micro/nanotwin structures and their corresponding diffraction patterns.

Original languageEnglish
Article number202907
JournalApplied Physics Letters
Volume94
Issue number20
DOIs
Publication statusPublished - 2009
Externally publishedYes

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