Abstract
The complexes (Et 4N) 2ZnBr nCl 4-n, (Et 4N) 2ZnBr nI 4-n (n = 1, 2, or 3), (Et 4N) 2ZnCl 2I 2, and (Et 4N) 2ZnClI 3 have been prepared, but (Et 4N) 2ZnCl 3I could not be characterised. X-Ray powder photography has shown that the bromochloro-complexes have structures similar to (Et 4N) 2ZnCl 4 and (Et 4N) 2ZnBr 4 but not to (Et 4N) 2ZnI 4, while the bromoiodo-complexes and (Et 4N) 2ZnClI 3 have structures similar to (Et 4N) 2ZnI 4. The infrared spectra (3100-2800 and 2000-750 cm. -1) of the complexes (Et 4N) 2ZnBr nCl 4-n (n = 0, 1, 2, 3, or 4) differ significantly from those of the iodo-complexes.
| Original language | English |
|---|---|
| Pages (from-to) | 463-464 |
| Number of pages | 2 |
| Journal | Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry |
| DOIs | |
| Publication status | Published - 1 Dec 1966 |
Cite this
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Tetraethylammonium tetrahalogenozincate(II) complexes with mixed halide ligands. / Deacon, G. B.; Taylor, F. B.
In: Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry, 01.12.1966, p. 463-464.Research output: Contribution to journal › Article › Research › peer-review
TY - JOUR
T1 - Tetraethylammonium tetrahalogenozincate(II) complexes with mixed halide ligands
AU - Deacon, G. B.
AU - Taylor, F. B.
PY - 1966/12/1
Y1 - 1966/12/1
N2 - The complexes (Et 4N) 2ZnBr nCl 4-n, (Et 4N) 2ZnBr nI 4-n (n = 1, 2, or 3), (Et 4N) 2ZnCl 2I 2, and (Et 4N) 2ZnClI 3 have been prepared, but (Et 4N) 2ZnCl 3I could not be characterised. X-Ray powder photography has shown that the bromochloro-complexes have structures similar to (Et 4N) 2ZnCl 4 and (Et 4N) 2ZnBr 4 but not to (Et 4N) 2ZnI 4, while the bromoiodo-complexes and (Et 4N) 2ZnClI 3 have structures similar to (Et 4N) 2ZnI 4. The infrared spectra (3100-2800 and 2000-750 cm. -1) of the complexes (Et 4N) 2ZnBr nCl 4-n (n = 0, 1, 2, 3, or 4) differ significantly from those of the iodo-complexes.
AB - The complexes (Et 4N) 2ZnBr nCl 4-n, (Et 4N) 2ZnBr nI 4-n (n = 1, 2, or 3), (Et 4N) 2ZnCl 2I 2, and (Et 4N) 2ZnClI 3 have been prepared, but (Et 4N) 2ZnCl 3I could not be characterised. X-Ray powder photography has shown that the bromochloro-complexes have structures similar to (Et 4N) 2ZnCl 4 and (Et 4N) 2ZnBr 4 but not to (Et 4N) 2ZnI 4, while the bromoiodo-complexes and (Et 4N) 2ZnClI 3 have structures similar to (Et 4N) 2ZnI 4. The infrared spectra (3100-2800 and 2000-750 cm. -1) of the complexes (Et 4N) 2ZnBr nCl 4-n (n = 0, 1, 2, 3, or 4) differ significantly from those of the iodo-complexes.
UR - http://www.scopus.com/inward/record.url?scp=37049122479&partnerID=8YFLogxK
U2 - 10.1039/J19660000463
DO - 10.1039/J19660000463
M3 - Article
SP - 463
EP - 464
JO - Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry
JF - Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry
SN - 0022-4944
ER -