Tetraethylammonium tetrahalogenozincate(II) complexes with mixed halide ligands

G. B. Deacon; F. B. Taylor

doi:10.1039/J19660000463

Tetraethylammonium tetrahalogenozincate(II) complexes with mixed halide ligands

G. B. Deacon, F. B. Taylor

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

3 Citations (Scopus)

Abstract

The complexes (Et ₄N) ₂ZnBr _nCl _4-n, (Et ₄N) ₂ZnBr _nI _4-n (n = 1, 2, or 3), (Et ₄N) ₂ZnCl ₂I ₂, and (Et ₄N) ₂ZnClI ₃ have been prepared, but (Et ₄N) ₂ZnCl ₃I could not be characterised. X-Ray powder photography has shown that the bromochloro-complexes have structures similar to (Et ₄N) ₂ZnCl ₄ and (Et ₄N) ₂ZnBr ₄ but not to (Et ₄N) ₂ZnI ₄, while the bromoiodo-complexes and (Et ₄N) ₂ZnClI ₃ have structures similar to (Et ₄N) ₂ZnI ₄. The infrared spectra (3100-2800 and 2000-750 cm. ^-1) of the complexes (Et ₄N) ₂ZnBr _nCl _4-n (n = 0, 1, 2, 3, or 4) differ significantly from those of the iodo-complexes.

Original language	English
Pages (from-to)	463-464
Number of pages	2
Journal	Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry
DOIs	https://doi.org/10.1039/J19660000463
Publication status	Published - 1 Dec 1966

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title = "Tetraethylammonium tetrahalogenozincate(II) complexes with mixed halide ligands",

abstract = "The complexes (Et 4N) 2ZnBr nCl 4-n, (Et 4N) 2ZnBr nI 4-n (n = 1, 2, or 3), (Et 4N) 2ZnCl 2I 2, and (Et 4N) 2ZnClI 3 have been prepared, but (Et 4N) 2ZnCl 3I could not be characterised. X-Ray powder photography has shown that the bromochloro-complexes have structures similar to (Et 4N) 2ZnCl 4 and (Et 4N) 2ZnBr 4 but not to (Et 4N) 2ZnI 4, while the bromoiodo-complexes and (Et 4N) 2ZnClI 3 have structures similar to (Et 4N) 2ZnI 4. The infrared spectra (3100-2800 and 2000-750 cm. -1) of the complexes (Et 4N) 2ZnBr nCl 4-n (n = 0, 1, 2, 3, or 4) differ significantly from those of the iodo-complexes.",

author = "Deacon, {G. B.} and Taylor, {F. B.}",

year = "1966",

month = dec,

day = "1",

doi = "10.1039/J19660000463",

language = "English",

pages = "463--464",

journal = "Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry",

issn = "0022-4944",

publisher = "The Royal Society of Chemistry",

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TY - JOUR

T1 - Tetraethylammonium tetrahalogenozincate(II) complexes with mixed halide ligands

AU - Deacon, G. B.

AU - Taylor, F. B.

PY - 1966/12/1

Y1 - 1966/12/1

N2 - The complexes (Et 4N) 2ZnBr nCl 4-n, (Et 4N) 2ZnBr nI 4-n (n = 1, 2, or 3), (Et 4N) 2ZnCl 2I 2, and (Et 4N) 2ZnClI 3 have been prepared, but (Et 4N) 2ZnCl 3I could not be characterised. X-Ray powder photography has shown that the bromochloro-complexes have structures similar to (Et 4N) 2ZnCl 4 and (Et 4N) 2ZnBr 4 but not to (Et 4N) 2ZnI 4, while the bromoiodo-complexes and (Et 4N) 2ZnClI 3 have structures similar to (Et 4N) 2ZnI 4. The infrared spectra (3100-2800 and 2000-750 cm. -1) of the complexes (Et 4N) 2ZnBr nCl 4-n (n = 0, 1, 2, 3, or 4) differ significantly from those of the iodo-complexes.

AB - The complexes (Et 4N) 2ZnBr nCl 4-n, (Et 4N) 2ZnBr nI 4-n (n = 1, 2, or 3), (Et 4N) 2ZnCl 2I 2, and (Et 4N) 2ZnClI 3 have been prepared, but (Et 4N) 2ZnCl 3I could not be characterised. X-Ray powder photography has shown that the bromochloro-complexes have structures similar to (Et 4N) 2ZnCl 4 and (Et 4N) 2ZnBr 4 but not to (Et 4N) 2ZnI 4, while the bromoiodo-complexes and (Et 4N) 2ZnClI 3 have structures similar to (Et 4N) 2ZnI 4. The infrared spectra (3100-2800 and 2000-750 cm. -1) of the complexes (Et 4N) 2ZnBr nCl 4-n (n = 0, 1, 2, 3, or 4) differ significantly from those of the iodo-complexes.

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U2 - 10.1039/J19660000463

DO - 10.1039/J19660000463

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JO - Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry

JF - Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry

SN - 0022-4944

ER -

Tetraethylammonium tetrahalogenozincate(II) complexes with mixed halide ligands

Abstract

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