TY - JOUR
T1 - Tetraethylammonium tetrahalogenozincate(II) complexes with mixed halide ligands
AU - Deacon, G. B.
AU - Taylor, F. B.
PY - 1966/12/1
Y1 - 1966/12/1
N2 - The complexes (Et
4N)
2ZnBr
nCl
4-n, (Et
4N)
2ZnBr
nI
4-n (n = 1, 2, or 3), (Et
4N)
2ZnCl
2I
2, and (Et
4N)
2ZnClI
3 have been prepared, but (Et
4N)
2ZnCl
3I could not be characterised. X-Ray powder photography has shown that the bromochloro-complexes have structures similar to (Et
4N)
2ZnCl
4 and (Et
4N)
2ZnBr
4 but not to (Et
4N)
2ZnI
4, while the bromoiodo-complexes and (Et
4N)
2ZnClI
3 have structures similar to (Et
4N)
2ZnI
4. The infrared spectra (3100-2800 and 2000-750 cm.
-1) of the complexes (Et
4N)
2ZnBr
nCl
4-n (n = 0, 1, 2, 3, or 4) differ significantly from those of the iodo-complexes.
AB - The complexes (Et
4N)
2ZnBr
nCl
4-n, (Et
4N)
2ZnBr
nI
4-n (n = 1, 2, or 3), (Et
4N)
2ZnCl
2I
2, and (Et
4N)
2ZnClI
3 have been prepared, but (Et
4N)
2ZnCl
3I could not be characterised. X-Ray powder photography has shown that the bromochloro-complexes have structures similar to (Et
4N)
2ZnCl
4 and (Et
4N)
2ZnBr
4 but not to (Et
4N)
2ZnI
4, while the bromoiodo-complexes and (Et
4N)
2ZnClI
3 have structures similar to (Et
4N)
2ZnI
4. The infrared spectra (3100-2800 and 2000-750 cm.
-1) of the complexes (Et
4N)
2ZnBr
nCl
4-n (n = 0, 1, 2, 3, or 4) differ significantly from those of the iodo-complexes.
UR - http://www.scopus.com/inward/record.url?scp=37049122479&partnerID=8YFLogxK
U2 - 10.1039/J19660000463
DO - 10.1039/J19660000463
M3 - Article
AN - SCOPUS:37049122479
SP - 463
EP - 464
JO - Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry
JF - Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry
SN - 0022-4944
ER -