Tetraethylammonium tetrahalogenozincate(II) complexes with mixed halide ligands

G. B. Deacon, F. B. Taylor

Research output: Contribution to journalArticleResearchpeer-review

Abstract

The complexes (Et 4N) 2ZnBr nCl 4-n, (Et 4N) 2ZnBr nI 4-n (n = 1, 2, or 3), (Et 4N) 2ZnCl 2I 2, and (Et 4N) 2ZnClI 3 have been prepared, but (Et 4N) 2ZnCl 3I could not be characterised. X-Ray powder photography has shown that the bromochloro-complexes have structures similar to (Et 4N) 2ZnCl 4 and (Et 4N) 2ZnBr 4 but not to (Et 4N) 2ZnI 4, while the bromoiodo-complexes and (Et 4N) 2ZnClI 3 have structures similar to (Et 4N) 2ZnI 4. The infrared spectra (3100-2800 and 2000-750 cm. -1) of the complexes (Et 4N) 2ZnBr nCl 4-n (n = 0, 1, 2, 3, or 4) differ significantly from those of the iodo-complexes.

Original languageEnglish
Pages (from-to)463-464
Number of pages2
JournalJournal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry
DOIs
Publication statusPublished - 1 Dec 1966

Cite this

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title = "Tetraethylammonium tetrahalogenozincate(II) complexes with mixed halide ligands",
abstract = "The complexes (Et 4N) 2ZnBr nCl 4-n, (Et 4N) 2ZnBr nI 4-n (n = 1, 2, or 3), (Et 4N) 2ZnCl 2I 2, and (Et 4N) 2ZnClI 3 have been prepared, but (Et 4N) 2ZnCl 3I could not be characterised. X-Ray powder photography has shown that the bromochloro-complexes have structures similar to (Et 4N) 2ZnCl 4 and (Et 4N) 2ZnBr 4 but not to (Et 4N) 2ZnI 4, while the bromoiodo-complexes and (Et 4N) 2ZnClI 3 have structures similar to (Et 4N) 2ZnI 4. The infrared spectra (3100-2800 and 2000-750 cm. -1) of the complexes (Et 4N) 2ZnBr nCl 4-n (n = 0, 1, 2, 3, or 4) differ significantly from those of the iodo-complexes.",
author = "Deacon, {G. B.} and Taylor, {F. B.}",
year = "1966",
month = "12",
day = "1",
doi = "10.1039/J19660000463",
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pages = "463--464",
journal = "Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry",
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publisher = "Royal Society of Chemistry (RSC)",

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Tetraethylammonium tetrahalogenozincate(II) complexes with mixed halide ligands. / Deacon, G. B.; Taylor, F. B.

In: Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry, 01.12.1966, p. 463-464.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - Tetraethylammonium tetrahalogenozincate(II) complexes with mixed halide ligands

AU - Deacon, G. B.

AU - Taylor, F. B.

PY - 1966/12/1

Y1 - 1966/12/1

N2 - The complexes (Et 4N) 2ZnBr nCl 4-n, (Et 4N) 2ZnBr nI 4-n (n = 1, 2, or 3), (Et 4N) 2ZnCl 2I 2, and (Et 4N) 2ZnClI 3 have been prepared, but (Et 4N) 2ZnCl 3I could not be characterised. X-Ray powder photography has shown that the bromochloro-complexes have structures similar to (Et 4N) 2ZnCl 4 and (Et 4N) 2ZnBr 4 but not to (Et 4N) 2ZnI 4, while the bromoiodo-complexes and (Et 4N) 2ZnClI 3 have structures similar to (Et 4N) 2ZnI 4. The infrared spectra (3100-2800 and 2000-750 cm. -1) of the complexes (Et 4N) 2ZnBr nCl 4-n (n = 0, 1, 2, 3, or 4) differ significantly from those of the iodo-complexes.

AB - The complexes (Et 4N) 2ZnBr nCl 4-n, (Et 4N) 2ZnBr nI 4-n (n = 1, 2, or 3), (Et 4N) 2ZnCl 2I 2, and (Et 4N) 2ZnClI 3 have been prepared, but (Et 4N) 2ZnCl 3I could not be characterised. X-Ray powder photography has shown that the bromochloro-complexes have structures similar to (Et 4N) 2ZnCl 4 and (Et 4N) 2ZnBr 4 but not to (Et 4N) 2ZnI 4, while the bromoiodo-complexes and (Et 4N) 2ZnClI 3 have structures similar to (Et 4N) 2ZnI 4. The infrared spectra (3100-2800 and 2000-750 cm. -1) of the complexes (Et 4N) 2ZnBr nCl 4-n (n = 0, 1, 2, 3, or 4) differ significantly from those of the iodo-complexes.

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DO - 10.1039/J19660000463

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JO - Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry

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