Tetrachlorido-1kCl,2k2 Cl,3kCl-bis[-μ-4-undecyl-1,4,7- triazacyclonon1-yl)acetato]-1k4 N,N′,N″,O: 2kO′;2kO′:-3k4 N,N′,N″,O-tricopper(II) dihydrate

Lilly Nagel, Craig M. Forsyth, Lisandra L. Martin

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Abstract

In the trinuclear title compound, [Cu3Cl4(C17H38N3O2)2]·2H2O or [Cu(AcC11tacn)Cl·H2O]2·CuCl2 [tacn is 1,4,7-triaza-cyclo-nonone], two Cu atoms are coordinated by a bifunctionalized 1-acetato-4-undecyl-1,4,7- triaza-cyclo-nonone (AcC11tacn) macrocycle and are five-coordinate, while the third Cu atom, located on a centre of inversion, bridges these two units between two keto O atoms, with two Cl atoms completing a four-coordinate square-planar geometry. The long C11 tails on the macrocycle create well ordered multilayer packing.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume63
Issue number8
DOIs
Publication statusPublished - 31 Jul 2007

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