Templated assembly of a µ6-CO32− dodecanuclear lanthanum dibenzoylmethanide hydroxido cluster with concomitant formation of phenylglyoxylate

Philip C. Andrews, Tobias Beck, Craig M. Forsyth, Benjamin H. Fraser, Peter C. Junk, Massimiliano Massi, Peter W. Roesky

Research output: Contribution to journalComment / DebateResearchpeer-review

Abstract

Reaction of LaCl3 and dibenzoylmethane (Ph2acacH) in methanol with an excess of triethylamine resulted in the unexpected formation of a dodecanuclear hydroxo-bridged La cluster templated by CO32− and phenylglyoxylate (Phgly), as determined by X-ray crystallography.

Original languageEnglish
Pages (from-to)5651-5654
Number of pages4
JournalDalton Transactions
Volume0
Issue number48
DOIs
Publication statusPublished - 4 Dec 2006

Cite this