Temperature-induced oriented growth of large area, few-layer 2D metal-organic framework nanosheets

Meipeng Jian; Huiyuan Liu; Tim Williams; Jisheng Ma; Huanting Wang; Xiwang Zhang

doi:10.1039/c7cc06988j

Temperature-induced oriented growth of large area, few-layer 2D metal-organic framework nanosheets

Meipeng Jian, Huiyuan Liu, Tim Williams, Jisheng Ma, Huanting Wang, Xiwang Zhang

Research output: Contribution to journal › Article › Research › peer-review

61 Citations (Scopus)

Abstract

The isolation of few-layer two-dimensional (2D) metal-organic framework (MOF) sheets has been achieved at an elevated solvothermal reaction temperature. The 2D porphyrin paddlewheel framework-1 (PPF-1) MOF nanosheets (NS) are ultrathin (2.5 nm) and have large lateral dimensions (over 2 μm). The yield of PPF-1 NS was also increased to 71.7% with increasing the reaction temperature. The results revealed that the formation of PPF-1 NS was attributed to the enlarged interlayer space and accelerated crystal growth rate along the lateral direction.

Original language	English
Pages (from-to)	13161-13164
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	98
DOIs	https://doi.org/10.1039/c7cc06988j
Publication status	Published - 21 Dec 2017

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10.1039/c7cc06988j

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title = "Temperature-induced oriented growth of large area, few-layer 2D metal-organic framework nanosheets",

abstract = "The isolation of few-layer two-dimensional (2D) metal-organic framework (MOF) sheets has been achieved at an elevated solvothermal reaction temperature. The 2D porphyrin paddlewheel framework-1 (PPF-1) MOF nanosheets (NS) are ultrathin (2.5 nm) and have large lateral dimensions (over 2 μm). The yield of PPF-1 NS was also increased to 71.7\% with increasing the reaction temperature. The results revealed that the formation of PPF-1 NS was attributed to the enlarged interlayer space and accelerated crystal growth rate along the lateral direction.",

author = "Meipeng Jian and Huiyuan Liu and Tim Williams and Jisheng Ma and Huanting Wang and Xiwang Zhang",

year = "2017",

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journal = "Chemical Communications",

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T1 - Temperature-induced oriented growth of large area, few-layer 2D metal-organic framework nanosheets

AU - Jian, Meipeng

AU - Liu, Huiyuan

AU - Williams, Tim

AU - Ma, Jisheng

AU - Wang, Huanting

AU - Zhang, Xiwang

PY - 2017/12/21

Y1 - 2017/12/21

N2 - The isolation of few-layer two-dimensional (2D) metal-organic framework (MOF) sheets has been achieved at an elevated solvothermal reaction temperature. The 2D porphyrin paddlewheel framework-1 (PPF-1) MOF nanosheets (NS) are ultrathin (2.5 nm) and have large lateral dimensions (over 2 μm). The yield of PPF-1 NS was also increased to 71.7% with increasing the reaction temperature. The results revealed that the formation of PPF-1 NS was attributed to the enlarged interlayer space and accelerated crystal growth rate along the lateral direction.

AB - The isolation of few-layer two-dimensional (2D) metal-organic framework (MOF) sheets has been achieved at an elevated solvothermal reaction temperature. The 2D porphyrin paddlewheel framework-1 (PPF-1) MOF nanosheets (NS) are ultrathin (2.5 nm) and have large lateral dimensions (over 2 μm). The yield of PPF-1 NS was also increased to 71.7% with increasing the reaction temperature. The results revealed that the formation of PPF-1 NS was attributed to the enlarged interlayer space and accelerated crystal growth rate along the lateral direction.

UR - https://www.scopus.com/pages/publications/85038231379

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DO - 10.1039/c7cc06988j

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SN - 1359-7345

VL - 53

SP - 13161

EP - 13164

JO - Chemical Communications

JF - Chemical Communications

IS - 98

ER -

Temperature-induced oriented growth of large area, few-layer 2D metal-organic framework nanosheets

Abstract

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Development of Solar-induced, Dark-active Photocatalytic Membranes for Water Disinfection

An X-ray scattering facility for advanced characterisation of natural and novel materials

Melbourne Centre for Nanofabrication (MCN)

Monash Centre for Electron Microscopy (MCEM)

Monash X-ray Platform (MXP)

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Temperature-induced oriented growth of large area, few-layer 2D metal-organic framework nanosheets

Abstract

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Projects

Development of Solar-induced, Dark-active Photocatalytic Membranes for Water Disinfection

An X-ray scattering facility for advanced characterisation of natural and novel materials

Equipment

Melbourne Centre for Nanofabrication (MCN)

Monash Centre for Electron Microscopy (MCEM)

Monash X-ray Platform (MXP)

Cite this