Temperature-induced oriented growth of large area, few-layer 2D metal-organic framework nanosheets

Meipeng Jian, Huiyuan Liu, Tim Williams, Jisheng Ma, Huanting Wang, Xiwang Zhang

Research output: Contribution to journalArticleResearchpeer-review

Abstract

The isolation of few-layer two-dimensional (2D) metal-organic framework (MOF) sheets has been achieved at an elevated solvothermal reaction temperature. The 2D porphyrin paddlewheel framework-1 (PPF-1) MOF nanosheets (NS) are ultrathin (2.5 nm) and have large lateral dimensions (over 2 μm). The yield of PPF-1 NS was also increased to 71.7% with increasing the reaction temperature. The results revealed that the formation of PPF-1 NS was attributed to the enlarged interlayer space and accelerated crystal growth rate along the lateral direction.

Original languageEnglish
Pages (from-to)13161-13164
Number of pages4
JournalChemical Communications
Volume53
Issue number98
DOIs
Publication statusPublished - 21 Dec 2017

Cite this

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title = "Temperature-induced oriented growth of large area, few-layer 2D metal-organic framework nanosheets",
abstract = "The isolation of few-layer two-dimensional (2D) metal-organic framework (MOF) sheets has been achieved at an elevated solvothermal reaction temperature. The 2D porphyrin paddlewheel framework-1 (PPF-1) MOF nanosheets (NS) are ultrathin (2.5 nm) and have large lateral dimensions (over 2 μm). The yield of PPF-1 NS was also increased to 71.7{\%} with increasing the reaction temperature. The results revealed that the formation of PPF-1 NS was attributed to the enlarged interlayer space and accelerated crystal growth rate along the lateral direction.",
author = "Meipeng Jian and Huiyuan Liu and Tim Williams and Jisheng Ma and Huanting Wang and Xiwang Zhang",
year = "2017",
month = "12",
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language = "English",
volume = "53",
pages = "13161--13164",
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Temperature-induced oriented growth of large area, few-layer 2D metal-organic framework nanosheets. / Jian, Meipeng; Liu, Huiyuan; Williams, Tim; Ma, Jisheng; Wang, Huanting; Zhang, Xiwang.

In: Chemical Communications, Vol. 53, No. 98, 21.12.2017, p. 13161-13164.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - Temperature-induced oriented growth of large area, few-layer 2D metal-organic framework nanosheets

AU - Jian, Meipeng

AU - Liu, Huiyuan

AU - Williams, Tim

AU - Ma, Jisheng

AU - Wang, Huanting

AU - Zhang, Xiwang

PY - 2017/12/21

Y1 - 2017/12/21

N2 - The isolation of few-layer two-dimensional (2D) metal-organic framework (MOF) sheets has been achieved at an elevated solvothermal reaction temperature. The 2D porphyrin paddlewheel framework-1 (PPF-1) MOF nanosheets (NS) are ultrathin (2.5 nm) and have large lateral dimensions (over 2 μm). The yield of PPF-1 NS was also increased to 71.7% with increasing the reaction temperature. The results revealed that the formation of PPF-1 NS was attributed to the enlarged interlayer space and accelerated crystal growth rate along the lateral direction.

AB - The isolation of few-layer two-dimensional (2D) metal-organic framework (MOF) sheets has been achieved at an elevated solvothermal reaction temperature. The 2D porphyrin paddlewheel framework-1 (PPF-1) MOF nanosheets (NS) are ultrathin (2.5 nm) and have large lateral dimensions (over 2 μm). The yield of PPF-1 NS was also increased to 71.7% with increasing the reaction temperature. The results revealed that the formation of PPF-1 NS was attributed to the enlarged interlayer space and accelerated crystal growth rate along the lateral direction.

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