Abstract
The isolation of few-layer two-dimensional (2D) metal-organic framework (MOF) sheets has been achieved at an elevated solvothermal reaction temperature. The 2D porphyrin paddlewheel framework-1 (PPF-1) MOF nanosheets (NS) are ultrathin (2.5 nm) and have large lateral dimensions (over 2 μm). The yield of PPF-1 NS was also increased to 71.7% with increasing the reaction temperature. The results revealed that the formation of PPF-1 NS was attributed to the enlarged interlayer space and accelerated crystal growth rate along the lateral direction.
| Original language | English |
|---|---|
| Pages (from-to) | 13161-13164 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 53 |
| Issue number | 98 |
| DOIs | |
| Publication status | Published - 21 Dec 2017 |
Cite this
}
Temperature-induced oriented growth of large area, few-layer 2D metal-organic framework nanosheets. / Jian, Meipeng; Liu, Huiyuan; Williams, Tim; Ma, Jisheng; Wang, Huanting; Zhang, Xiwang.
In: Chemical Communications, Vol. 53, No. 98, 21.12.2017, p. 13161-13164.Research output: Contribution to journal › Article › Research › peer-review
TY - JOUR
T1 - Temperature-induced oriented growth of large area, few-layer 2D metal-organic framework nanosheets
AU - Jian, Meipeng
AU - Liu, Huiyuan
AU - Williams, Tim
AU - Ma, Jisheng
AU - Wang, Huanting
AU - Zhang, Xiwang
PY - 2017/12/21
Y1 - 2017/12/21
N2 - The isolation of few-layer two-dimensional (2D) metal-organic framework (MOF) sheets has been achieved at an elevated solvothermal reaction temperature. The 2D porphyrin paddlewheel framework-1 (PPF-1) MOF nanosheets (NS) are ultrathin (2.5 nm) and have large lateral dimensions (over 2 μm). The yield of PPF-1 NS was also increased to 71.7% with increasing the reaction temperature. The results revealed that the formation of PPF-1 NS was attributed to the enlarged interlayer space and accelerated crystal growth rate along the lateral direction.
AB - The isolation of few-layer two-dimensional (2D) metal-organic framework (MOF) sheets has been achieved at an elevated solvothermal reaction temperature. The 2D porphyrin paddlewheel framework-1 (PPF-1) MOF nanosheets (NS) are ultrathin (2.5 nm) and have large lateral dimensions (over 2 μm). The yield of PPF-1 NS was also increased to 71.7% with increasing the reaction temperature. The results revealed that the formation of PPF-1 NS was attributed to the enlarged interlayer space and accelerated crystal growth rate along the lateral direction.
UR - http://www.scopus.com/inward/record.url?scp=85038231379&partnerID=8YFLogxK
U2 - 10.1039/c7cc06988j
DO - 10.1039/c7cc06988j
M3 - Article
VL - 53
SP - 13161
EP - 13164
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 98
ER -