Task-specific thioglycolate ionic liquids for heavy metal extraction: synthesis, extraction efficacies and recycling properties

Sonja Platzer, Mega Kar, Raphlin Leyma, Sonia Chib, Alexander Roller, Franz Jirsa, Regina Krachler, Douglas Macfarlane, Wolfgang Kandioller, Bernhard K. Keppler

Research output: Contribution to journalArticleResearchpeer-review

42 Citations (Scopus)

Abstract

Eight novel task-specific ionic liquids (TSILs) based on the thioglycolate anion designed for heavy metal extraction have been prepared and characterized by 1H and 13C NMR, UV-Vis, infrared, ESI-MS, conductivity, viscosity, density and thermal properties. Evaluation of their time-resolved extraction abilities towards cadmium(II) and copper(II) in aqueous solutions have been investigated where distribution ratios up to 1200 were observed. For elucidation of the IL extraction mode, crystals were grown where Cd(II) was converted with an excess of S-butyl thioglycolate. It was found by X-ray diffraction analysis that cadmium is coordinated by five oxygen and one sulfur donor atoms provided by two thioglycolate molecules and one water molecule. Leaching behavior of the hydrophobic ionic liquids into aqueous systems was studied by TOC (total dissolved organic carbon) measurements. Additionally, the immobilization on polypropylene was elucidated and revealed slower metal extraction rates and similar leaching behavior. Finally, recovery processes for cadmium and copper after extraction were performed and recyclability was successfully proven for both metals.

Original languageEnglish
Pages (from-to)241-249
Number of pages9
JournalJournal of Hazardous Materials
Volume324
DOIs
Publication statusPublished - 15 Feb 2017

Keywords

  • Heavy metal extraction
  • Immobilization
  • Reusability
  • Task-specific ionic liquids
  • Thioglycolic acid

Cite this