Tailored interface engineering of Co₃Fe₇/Fe₃C heterojunctions for enhancing oxygen reduction reaction in zinc-air batteries

The rational construction of highly active and robust non-precious metal oxygen reduction electrocatalysts is a vital factor to facilitate commercial applications of Zn-air batteries. In this study, a precise and stable heterostructure, comprised of a coupling of Co₃Fe₇ and Fe₃C, was constructed through an interface engineering-induced strategy. The coordination polymerization of the resin with the bimetallic components was meticulously regulated to control the interfacial characteristics of the heterostructure. The synergistic interfacial effects of the heterostructure successfully facilitated electron coupling and rapid charge transfer. Consequently, the optimized CST-FeCo displayed superb oxygen reduction catalytic activity with a positive half-wave potential of 0.855 V vs. RHE. Furthermore, the CST-FeCo air electrode of the liquid zinc-air battery revealed a large specific capacity of 805.6 mAh g_Zn^-1, corresponding to a remarkable peak power density of 162.7 mW cm⁻², and a long charge/discharge cycle stability of 220 h, surpassing that of the commercial Pt/C catalyst.