Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand

Marko Perić, Sara H. Kyne, Maja Gruden, Marko Rodić, Dejan Jeremić, Dalibor M. Stanković, Ilija Brčeski

Research output: Contribution to journalArticleResearchpeer-review

Abstract

In this work we present the synthesis, and experimental and theoretical analysis of a binuclear nickel(II) complex coordinated to a new phthalazine dihydrazone-based ligand. Single-crystal X-ray diffraction analysis of the metal complex shows that the coordination geometry around each nickel(II) atom is distorted octahedral. DFT calculations predict that the magnetic exchange coupling constant of the binuclear nickel(II) complex is predominantly anti-ferromagnetic.

Original languageEnglish
Pages (from-to)1241-1248
Number of pages8
JournalMonatshefte fur Chemie
Volume150
Issue number7
DOIs
Publication statusPublished - 1 Jul 2019
Externally publishedYes

Keywords

  • Binuclear complex
  • Density functional theory
  • Magnetic properties
  • X-ray structure determination

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