Synthesis of zirconium tetrafluoride using ammonium bifluoride melts

D. R. MacFarlane; P. J. Mineely; P. J. Newman

doi:10.1016/S0022-3093(05)80792-6

Synthesis of zirconium tetrafluoride using ammonium bifluoride melts

D. R. MacFarlane, P. J. Mineely, P. J. Newman

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

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Abstract

A novel method for preparation of ZrF₄ is described which makes use of molten ammonium bifluoride as the fluorinating agent. A variety of metal salts can be used in this procedure. There are several advantages in using this method compared with previously described methods for the preparation of ZrF₄, including complete reaction and mild reaction conditions which allow the use of contamination free fluoropolymer apparatus.

Original language	English
Pages (from-to)	335-339
Number of pages	5
Journal	Journal of Non-Crystalline Solids
Volume	140
Issue number	C
DOIs	https://doi.org/10.1016/S0022-3093(05)80792-6
Publication status	Published - 1 Jan 1992

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title = "Synthesis of zirconium tetrafluoride using ammonium bifluoride melts",

abstract = "A novel method for preparation of ZrF4 is described which makes use of molten ammonium bifluoride as the fluorinating agent. A variety of metal salts can be used in this procedure. There are several advantages in using this method compared with previously described methods for the preparation of ZrF4, including complete reaction and mild reaction conditions which allow the use of contamination free fluoropolymer apparatus.",

author = "MacFarlane, {D. R.} and Mineely, {P. J.} and Newman, {P. J.}",

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AU - MacFarlane, D. R.

AU - Mineely, P. J.

AU - Newman, P. J.

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N2 - A novel method for preparation of ZrF4 is described which makes use of molten ammonium bifluoride as the fluorinating agent. A variety of metal salts can be used in this procedure. There are several advantages in using this method compared with previously described methods for the preparation of ZrF4, including complete reaction and mild reaction conditions which allow the use of contamination free fluoropolymer apparatus.

AB - A novel method for preparation of ZrF4 is described which makes use of molten ammonium bifluoride as the fluorinating agent. A variety of metal salts can be used in this procedure. There are several advantages in using this method compared with previously described methods for the preparation of ZrF4, including complete reaction and mild reaction conditions which allow the use of contamination free fluoropolymer apparatus.

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ER -

Synthesis of zirconium tetrafluoride using ammonium bifluoride melts

Abstract

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