TY - JOUR
T1 - Synthesis of arylbismuth(III) sulfonates from triarylbismuth compounds and arenesulfonic acids or sulfur trioxide
AU - Deacon, G. B.
AU - Felder, P. W.
AU - Domagala, M
AU - Huber, Friedo E
AU - Ruther, Robert
PY - 1986/3/3
Y1 - 1986/3/3
N2 - Reactions of triphenyt- and tri-p-tolyl-bismuth with the appropriate arenesulfonic acids give the diarylbismuth(III) sulfonates, R2BiO3SR′ (R, R′ = Ph or p-MeC6H4). (p-MeC6H4)3Bi reacts with PhSO3H (mole ratio, 1:2) under more aggressive conditions to give impure p-MeC6H4Bi(O3SPh)2. From reactions of the bismuthines with sulfur tri- oxide, Ph2BiO3SPh (not Ph3Bi·SO3 as previously indicated [1]) and a mixture of (p-MeC6H4)2BiO3S- p-MeC6H4 and p-MeC6H4Bi(O3S-p-MeC6H4)2 have been obtained. On prolonged standing, Ph2BiO3SR′ (R′ = Ph or p-MeC6H4) compounds decompose into BiO(O3SR′) and a small amount of triphenylbismuth.
AB - Reactions of triphenyt- and tri-p-tolyl-bismuth with the appropriate arenesulfonic acids give the diarylbismuth(III) sulfonates, R2BiO3SR′ (R, R′ = Ph or p-MeC6H4). (p-MeC6H4)3Bi reacts with PhSO3H (mole ratio, 1:2) under more aggressive conditions to give impure p-MeC6H4Bi(O3SPh)2. From reactions of the bismuthines with sulfur tri- oxide, Ph2BiO3SPh (not Ph3Bi·SO3 as previously indicated [1]) and a mixture of (p-MeC6H4)2BiO3S- p-MeC6H4 and p-MeC6H4Bi(O3S-p-MeC6H4)2 have been obtained. On prolonged standing, Ph2BiO3SR′ (R′ = Ph or p-MeC6H4) compounds decompose into BiO(O3SR′) and a small amount of triphenylbismuth.
UR - http://www.scopus.com/inward/record.url?scp=4243740626&partnerID=8YFLogxK
U2 - 10.1016/S0020-1693(00)86855-3
DO - 10.1016/S0020-1693(00)86855-3
M3 - Article
AN - SCOPUS:4243740626
SN - 0020-1693
VL - 113
SP - 43
EP - 46
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 1
ER -