Synthesis of 1,3-disubstituted bicyclo[1.1.1]pentanes by cross-coupling induced by transition metals - formation of C-C bonds

Tomohiro Yasukawa; Katja S. Håheim; Janine Cossy

doi:10.1039/d3ob01036h

Synthesis of 1,3-disubstituted bicyclo[1.1.1]pentanes by cross-coupling induced by transition metals - formation of C-C bonds

Tomohiro Yasukawa, Katja S. Håheim, Janine Cossy

Research output: Contribution to journal › Review Article › Research › peer-review

9 Citations (Scopus)

Abstract

The synthesis of 1,3-disubstituted bicyclo[1.1.1]pentanes (BCPs), by forming a C-C bond, can be achieved by cross-coupling reactions using transition metal catalysts. Two main strategies are described to access these 1,3-disubstituted BCPs, either from nucleophilic BCPs or electrophilic BCPs. Mechanisms are included where relevant.

Original language	English
Pages (from-to)	7666-7680
Number of pages	15
Journal	Organic & Biomolecular Chemistry
Volume	21
Issue number	38
DOIs	https://doi.org/10.1039/d3ob01036h
Publication status	Published - 14 Oct 2023
Externally published	Yes

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title = "Synthesis of 1,3-disubstituted bicyclo[1.1.1]pentanes by cross-coupling induced by transition metals - formation of C-C bonds",

abstract = "The synthesis of 1,3-disubstituted bicyclo[1.1.1]pentanes (BCPs), by forming a C-C bond, can be achieved by cross-coupling reactions using transition metal catalysts. Two main strategies are described to access these 1,3-disubstituted BCPs, either from nucleophilic BCPs or electrophilic BCPs. Mechanisms are included where relevant.",

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AU - Yasukawa, Tomohiro

AU - Håheim, Katja S.

AU - Cossy, Janine

PY - 2023/10/14

Y1 - 2023/10/14

N2 - The synthesis of 1,3-disubstituted bicyclo[1.1.1]pentanes (BCPs), by forming a C-C bond, can be achieved by cross-coupling reactions using transition metal catalysts. Two main strategies are described to access these 1,3-disubstituted BCPs, either from nucleophilic BCPs or electrophilic BCPs. Mechanisms are included where relevant.

AB - The synthesis of 1,3-disubstituted bicyclo[1.1.1]pentanes (BCPs), by forming a C-C bond, can be achieved by cross-coupling reactions using transition metal catalysts. Two main strategies are described to access these 1,3-disubstituted BCPs, either from nucleophilic BCPs or electrophilic BCPs. Mechanisms are included where relevant.

UR - https://www.scopus.com/pages/publications/85172174770

U2 - 10.1039/d3ob01036h

DO - 10.1039/d3ob01036h

M3 - Review Article

AN - SCOPUS:85172174770

SN - 1477-0520

VL - 21

SP - 7666

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JO - Organic & Biomolecular Chemistry

JF - Organic & Biomolecular Chemistry

IS - 38

ER -

Synthesis of 1,3-disubstituted bicyclo[1.1.1]pentanes by cross-coupling induced by transition metals - formation of C-C bonds

Abstract

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