Synthesis, nmr spectroscopic studies, and X-ray structures of platinum(II) coordination complexes of the organophosphorus cage compounds P4C4But4 and P5C5But5

Vinicius Caliman; Peter B. Hitchcock; Cameron Jones; John F. Nixon

doi:10.1080/10426509608046374

Synthesis, nmr spectroscopic studies, and X-ray structures of platinum(II) coordination complexes of the organophosphorus cage compounds P₄C₄Bu^t₄ and P₅C₅Bu^t₅

Vinicius Caliman, Peter B. Hitchcock, Cameron Jones, John F. Nixon

Research output: Contribution to journal › Article › Research › peer-review

4 Citations (Scopus)

Abstract

The first examples of platinum(II) complexes of the P₄C₄Bu^t₄ and P₅C₅Bu^t₅ "cages" are described and detailed nmr and X-ray crystallographic structural studies have been carried out on the complexes trans-[PtCl₂(PR₃)(P⁴C⁴Bu ^t₄)], trans-[{PtCl₂(PR₃)}₂₂(P ₄C₄Bu^t₄)], (R = Et, Bu), and trans-[PtCl₂(PEt₃)-(P₅C₅Bu ^t₅)].

Original language	English
Pages (from-to)	15-37
Number of pages	23
Journal	Phosphorus, Sulfur and Silicon and the Related Elements
Volume	113
Issue number	1-4
DOIs	https://doi.org/10.1080/10426509608046374
Publication status	Published - 1 Jan 1996
Externally published	Yes

Keywords

NMR studies
Organophosphorus cage compounds
PCBu
Platinum complexes
X-ray structure

Access to Document

10.1080/10426509608046374

Cite this

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title = "Synthesis, nmr spectroscopic studies, and X-ray structures of platinum(II) coordination complexes of the organophosphorus cage compounds P4C4But4 and P5C5But5",

abstract = "The first examples of platinum(II) complexes of the P4C4But4 and P5C5But5 {"}cages{"} are described and detailed nmr and X-ray crystallographic structural studies have been carried out on the complexes trans-[PtCl2(PR3)(P4C4Bu t4)], trans-[{PtCl2(PR3)}22(P 4C4But4)], (R = Et, Bu), and trans-[PtCl2(PEt3)-(P5C5Bu t5)].",

keywords = "NMR studies, Organophosphorus cage compounds, PCBu, Platinum complexes, X-ray structure",

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Synthesis, nmr spectroscopic studies, and X-ray structures of platinum(II) coordination complexes of the organophosphorus cage compounds P₄C₄Bu^t₄ and P₅C₅Bu^t₅. / Caliman, Vinicius; Hitchcock, Peter B.; Jones, Cameron et al.
In: Phosphorus, Sulfur and Silicon and the Related Elements, Vol. 113, No. 1-4, 01.01.1996, p. 15-37.

Research output: Contribution to journal › Article › Research › peer-review

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T1 - Synthesis, nmr spectroscopic studies, and X-ray structures of platinum(II) coordination complexes of the organophosphorus cage compounds P4C4But4 and P5C5But5

AU - Caliman, Vinicius

AU - Hitchcock, Peter B.

AU - Jones, Cameron

AU - Nixon, John F.

PY - 1996/1/1

Y1 - 1996/1/1

N2 - The first examples of platinum(II) complexes of the P4C4But4 and P5C5But5 "cages" are described and detailed nmr and X-ray crystallographic structural studies have been carried out on the complexes trans-[PtCl2(PR3)(P4C4Bu t4)], trans-[{PtCl2(PR3)}22(P 4C4But4)], (R = Et, Bu), and trans-[PtCl2(PEt3)-(P5C5Bu t5)].

AB - The first examples of platinum(II) complexes of the P4C4But4 and P5C5But5 "cages" are described and detailed nmr and X-ray crystallographic structural studies have been carried out on the complexes trans-[PtCl2(PR3)(P4C4Bu t4)], trans-[{PtCl2(PR3)}22(P 4C4But4)], (R = Et, Bu), and trans-[PtCl2(PEt3)-(P5C5Bu t5)].

KW - NMR studies

KW - Organophosphorus cage compounds

KW - PCBu

KW - Platinum complexes

KW - X-ray structure

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