Abstract
The first examples of platinum(II) complexes of the P4C4But4 and P5C5But5 "cages" are described and detailed nmr and X-ray crystallographic structural studies have been carried out on the complexes trans-[PtCl2(PR3)(P4C4Bu t4)], trans-[{PtCl2(PR3)}22(P 4C4But4)], (R = Et, Bu), and trans-[PtCl2(PEt3)-(P5C5Bu t5)].
Original language | English |
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Pages (from-to) | 15-37 |
Number of pages | 23 |
Journal | Phosphorus, Sulfur and Silicon and the Related Elements |
Volume | 113 |
Issue number | 1-4 |
DOIs | |
Publication status | Published - 1 Jan 1996 |
Externally published | Yes |
Keywords
- NMR studies
- Organophosphorus cage compounds
- PCBu
- Platinum complexes
- X-ray structure