Synthesis, characterization and X-Ray crystal structure of the tri aqua (3-Hydroxy-5-Hydroxymethyl-2-Methylpyridine- 4-Carboxaldehyde-3- Methylisotiosemicarbazone: k3, O3, N7, N 10) Ni(II) nitrate

Violeta Jevtovic; Dragoslav Vidovic

doi:10.1007/s10870-010-9746-2

Synthesis, characterization and X-Ray crystal structure of the tri aqua (3-Hydroxy-5-Hydroxymethyl-2-Methylpyridine- 4-Carboxaldehyde-3- Methylisotiosemicarbazone: k3, O3, N7, N 10) Ni(II) nitrate

Violeta Jevtovic
, Dragoslav Vidovic

Research output: Contribution to journal › Review Article › Research › peer-review

12 Citations (Scopus)

Abstract

The title complex triaqua (3-hydroxy-5-hydroxymethyl- 2-methylpyridine-4- carboxaldehyde-3-methylisothiosemicarbazone- k³,O³,N ⁷,N¹⁰)Ni(II) nitrate ([Ni(PLITSC) (H₂O) ₃](NO₃)₂, 1) represents the second transition metal complex incorporating an isothiosemicarbazide-pyridoxal based Schiff base that has been crystallographically characterized. Complex 1 crystallizes in a P21/n space group,with lattice constants: a = 11.2254(1) Å , b = 12.9941(2) Å , c = 12.8663(2), β = 96,7713(5)°, V = 1863.64(4) Å ³, Z = 4, F(000) = 1016, R₁ = 0.0681, wR ₂ = 0.1201. The central Ni(II) cation is found in a six-coordinate octahedral geometry formed by the tridentate Schiff base ligand PLITSC and three water molecules. The identity of 1 was further confirmed by elemental analysis, IR spectra, and conductometric and magnetochemical measurements.

Original language	English
Pages (from-to)	794-798
Number of pages	5
Journal	Journal of Chemical Crystallography
Volume	40
Issue number	9
DOIs	https://doi.org/10.1007/s10870-010-9746-2
Publication status	Published - 1 Sept 2010
Externally published	Yes

Keywords

Characterization
Crystal structure
Ni(II) complex
Pyridoxal-S-methylisothiosemicarbazone
Synthesis

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10.1007/s10870-010-9746-2

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@article{7efebac2e9b14c8eb33b5e08b3d34e56,

title = "Synthesis, characterization and X-Ray crystal structure of the tri aqua (3-Hydroxy-5-Hydroxymethyl-2-Methylpyridine- 4-Carboxaldehyde-3- Methylisotiosemicarbazone: k3, O3, N7, N 10) Ni(II) nitrate",

abstract = "The title complex triaqua (3-hydroxy-5-hydroxymethyl- 2-methylpyridine-4- carboxaldehyde-3-methylisothiosemicarbazone- k3,O3,N 7,N10)Ni(II) nitrate ([Ni(PLITSC) (H2O) 3](NO3)2, 1) represents the second transition metal complex incorporating an isothiosemicarbazide-pyridoxal based Schiff base that has been crystallographically characterized. Complex 1 crystallizes in a P21/n space group,with lattice constants: a = 11.2254(1) {\AA} , b = 12.9941(2) {\AA} , c = 12.8663(2), β = 96,7713(5)°, V = 1863.64(4) {\AA} 3, Z = 4, F(000) = 1016, R1 = 0.0681, wR 2 = 0.1201. The central Ni(II) cation is found in a six-coordinate octahedral geometry formed by the tridentate Schiff base ligand PLITSC and three water molecules. The identity of 1 was further confirmed by elemental analysis, IR spectra, and conductometric and magnetochemical measurements.",

keywords = "Characterization, Crystal structure, Ni(II) complex, Pyridoxal-S-methylisothiosemicarbazone, Synthesis",

author = "Violeta Jevtovic and Dragoslav Vidovic",

year = "2010",

month = sep,

day = "1",

doi = "10.1007/s10870-010-9746-2",

language = "English",

volume = "40",

pages = "794--798",

journal = "Journal of Chemical Crystallography",

issn = "1074-1542",

publisher = "Springer-Verlag London Ltd.",

number = "9",

}

Synthesis, characterization and X-Ray crystal structure of the tri aqua (3-Hydroxy-5-Hydroxymethyl-2-Methylpyridine- 4-Carboxaldehyde-3- Methylisotiosemicarbazone: k3, O3, N7, N 10) Ni(II) nitrate. / Jevtovic, Violeta; Vidovic, Dragoslav.
In: Journal of Chemical Crystallography, Vol. 40, No. 9, 01.09.2010, p. 794-798.

Research output: Contribution to journal › Review Article › Research › peer-review

TY - JOUR

T1 - Synthesis, characterization and X-Ray crystal structure of the tri aqua (3-Hydroxy-5-Hydroxymethyl-2-Methylpyridine- 4-Carboxaldehyde-3- Methylisotiosemicarbazone

T2 - k3, O3, N7, N 10) Ni(II) nitrate

AU - Jevtovic, Violeta

AU - Vidovic, Dragoslav

PY - 2010/9/1

Y1 - 2010/9/1

N2 - The title complex triaqua (3-hydroxy-5-hydroxymethyl- 2-methylpyridine-4- carboxaldehyde-3-methylisothiosemicarbazone- k3,O3,N 7,N10)Ni(II) nitrate ([Ni(PLITSC) (H2O) 3](NO3)2, 1) represents the second transition metal complex incorporating an isothiosemicarbazide-pyridoxal based Schiff base that has been crystallographically characterized. Complex 1 crystallizes in a P21/n space group,with lattice constants: a = 11.2254(1) Å , b = 12.9941(2) Å , c = 12.8663(2), β = 96,7713(5)°, V = 1863.64(4) Å 3, Z = 4, F(000) = 1016, R1 = 0.0681, wR 2 = 0.1201. The central Ni(II) cation is found in a six-coordinate octahedral geometry formed by the tridentate Schiff base ligand PLITSC and three water molecules. The identity of 1 was further confirmed by elemental analysis, IR spectra, and conductometric and magnetochemical measurements.

AB - The title complex triaqua (3-hydroxy-5-hydroxymethyl- 2-methylpyridine-4- carboxaldehyde-3-methylisothiosemicarbazone- k3,O3,N 7,N10)Ni(II) nitrate ([Ni(PLITSC) (H2O) 3](NO3)2, 1) represents the second transition metal complex incorporating an isothiosemicarbazide-pyridoxal based Schiff base that has been crystallographically characterized. Complex 1 crystallizes in a P21/n space group,with lattice constants: a = 11.2254(1) Å , b = 12.9941(2) Å , c = 12.8663(2), β = 96,7713(5)°, V = 1863.64(4) Å 3, Z = 4, F(000) = 1016, R1 = 0.0681, wR 2 = 0.1201. The central Ni(II) cation is found in a six-coordinate octahedral geometry formed by the tridentate Schiff base ligand PLITSC and three water molecules. The identity of 1 was further confirmed by elemental analysis, IR spectra, and conductometric and magnetochemical measurements.

KW - Characterization

KW - Crystal structure

KW - Ni(II) complex

KW - Pyridoxal-S-methylisothiosemicarbazone

KW - Synthesis

UR - https://www.scopus.com/pages/publications/78649766551

U2 - 10.1007/s10870-010-9746-2

DO - 10.1007/s10870-010-9746-2

M3 - Review Article

AN - SCOPUS:78649766551

SN - 1074-1542

VL - 40

SP - 794

EP - 798

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

IS - 9

ER -

Synthesis, characterization and X-Ray crystal structure of the tri aqua (3-Hydroxy-5-Hydroxymethyl-2-Methylpyridine- 4-Carboxaldehyde-3- Methylisotiosemicarbazone: k3, O3, N7, N 10) Ni(II) nitrate

Abstract

Keywords

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