TY - JOUR
T1 - Synthesis, characterization and X-Ray crystal structure of the tri aqua (3-Hydroxy-5-Hydroxymethyl-2-Methylpyridine- 4-Carboxaldehyde-3- Methylisotiosemicarbazone
T2 - k3, O3, N7, N 10) Ni(II) nitrate
AU - Jevtovic, Violeta
AU - Vidovic, Dragoslav
PY - 2010/9/1
Y1 - 2010/9/1
N2 - The title complex triaqua (3-hydroxy-5-hydroxymethyl- 2-methylpyridine-4- carboxaldehyde-3-methylisothiosemicarbazone- k3,O3,N 7,N10)Ni(II) nitrate ([Ni(PLITSC) (H2O) 3](NO3)2, 1) represents the second transition metal complex incorporating an isothiosemicarbazide-pyridoxal based Schiff base that has been crystallographically characterized. Complex 1 crystallizes in a P21/n space group,with lattice constants: a = 11.2254(1) Å , b = 12.9941(2) Å , c = 12.8663(2), β = 96,7713(5)°, V = 1863.64(4) Å 3, Z = 4, F(000) = 1016, R1 = 0.0681, wR 2 = 0.1201. The central Ni(II) cation is found in a six-coordinate octahedral geometry formed by the tridentate Schiff base ligand PLITSC and three water molecules. The identity of 1 was further confirmed by elemental analysis, IR spectra, and conductometric and magnetochemical measurements.
AB - The title complex triaqua (3-hydroxy-5-hydroxymethyl- 2-methylpyridine-4- carboxaldehyde-3-methylisothiosemicarbazone- k3,O3,N 7,N10)Ni(II) nitrate ([Ni(PLITSC) (H2O) 3](NO3)2, 1) represents the second transition metal complex incorporating an isothiosemicarbazide-pyridoxal based Schiff base that has been crystallographically characterized. Complex 1 crystallizes in a P21/n space group,with lattice constants: a = 11.2254(1) Å , b = 12.9941(2) Å , c = 12.8663(2), β = 96,7713(5)°, V = 1863.64(4) Å 3, Z = 4, F(000) = 1016, R1 = 0.0681, wR 2 = 0.1201. The central Ni(II) cation is found in a six-coordinate octahedral geometry formed by the tridentate Schiff base ligand PLITSC and three water molecules. The identity of 1 was further confirmed by elemental analysis, IR spectra, and conductometric and magnetochemical measurements.
KW - Characterization
KW - Crystal structure
KW - Ni(II) complex
KW - Pyridoxal-S-methylisothiosemicarbazone
KW - Synthesis
UR - http://www.scopus.com/inward/record.url?scp=78649766551&partnerID=8YFLogxK
U2 - 10.1007/s10870-010-9746-2
DO - 10.1007/s10870-010-9746-2
M3 - Review Article
AN - SCOPUS:78649766551
VL - 40
SP - 794
EP - 798
JO - Journal of Chemical Crystallography
JF - Journal of Chemical Crystallography
SN - 1074-1542
IS - 9
ER -