Synthesis, characterisation and fluxional behaviour of [Ni(η5-P2C3Bu3t) (η3-P2C3Bu3t)]

F. Geoffrey N. Cloke, Kevin R. Flower, Cameron Jones, Robson M. Matos, John F. Nixon

Research output: Contribution to journalArticleResearchpeer-review

23 Citations (Scopus)

Abstract

Treatment of either [Na(DME)3][P2C3Bu3t] or [Yb(P2C3Bu3t)2] with [NiBr2(DME)2] affords the title compound which displays η5--η3-"ring slippage" behaviour in solution.

Original languageEnglish
JournalJournal of Organometallic Chemistry
Volume487
Issue number1-2
DOIs
Publication statusPublished - 8 Feb 1995
Externally publishedYes

Keywords

  • Fluxionality
  • Nickel
  • Polyphospholyl ligands
  • Ring slippage

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