Synthesis and structure of [{Sb(μ-NCy)}2(μ-N)]3(Li·THF)3- (LiN=NH), containing a macrocyclic [{Sb(μ-NCy)}2N]33- trianion

Felipe García; David J. Linton; Mary McPartlin; Alexander Rothenberger; Andrew E.H. Wheatley; Dominic S. Wright

doi:10.1039/b110984g

Synthesis and structure of [{Sb(μ-NCy)}₂(μ-N)]₃(Li·THF)₃- (LiN=NH), containing a macrocyclic [{Sb(μ-NCy)}₂N]₃^3- trianion

Felipe García
, David J. Linton
, Mary McPartlin
, Alexander Rothenberger
, Andrew E.H. Wheatley
, Dominic S. Wright

Research output: Contribution to journal › Article › Research › peer-review

10 Citations (Scopus)

Abstract

Reaction of the Sb(III) dimer [Me₂NSb(μ-NCy)]₂ with Li-NH₂ (1:2 equivalents, respectively) gives [{Sb(μ-NCy)}₂N]₃-(Li·THF)₃ (LiN=NH)·0.25(dioxane) 4, in which four Li⁺ cations are coordinated within the trimeric cavity of the macrocyclic trianion [{Sb(μ-NCy)}₂N]₃^3-.

Original language	English
Pages (from-to)	481-483
Number of pages	3
Journal	Dalton Transactions
Issue number	4
DOIs	https://doi.org/10.1039/b110984g
Publication status	Published - 2002
Externally published	Yes

Access to Document

10.1039/b110984g

Cite this

@article{80c7a7c282f14f16b8d2f934e695a418,

title = "Synthesis and structure of [\{Sb(μ-NCy)\}2(μ-N)]3(Li·THF)3- (LiN=NH), containing a macrocyclic [\{Sb(μ-NCy)\}2N]33- trianion",

abstract = "Reaction of the Sb(III) dimer [Me2NSb(μ-NCy)]2 with Li-NH2 (1:2 equivalents, respectively) gives [\{Sb(μ-NCy)\}2N]3-(Li·THF)3 (LiN=NH)·0.25(dioxane) 4, in which four Li+ cations are coordinated within the trimeric cavity of the macrocyclic trianion [\{Sb(μ-NCy)\}2N]33-.",

author = "Felipe Garc{\'i}a and Linton, \{David J.\} and Mary McPartlin and Alexander Rothenberger and Wheatley, \{Andrew E.H.\} and Wright, \{Dominic S.\}",

year = "2002",

doi = "10.1039/b110984g",

language = "English",

pages = "481--483",

journal = "Dalton Transactions",

issn = "1470-479X",

publisher = "The Royal Society of Chemistry",

number = "4",

}

TY - JOUR

T1 - Synthesis and structure of [{Sb(μ-NCy)}2(μ-N)]3(Li·THF)3- (LiN=NH), containing a macrocyclic [{Sb(μ-NCy)}2N]33- trianion

AU - García, Felipe

AU - Linton, David J.

AU - McPartlin, Mary

AU - Rothenberger, Alexander

AU - Wheatley, Andrew E.H.

AU - Wright, Dominic S.

PY - 2002

Y1 - 2002

N2 - Reaction of the Sb(III) dimer [Me2NSb(μ-NCy)]2 with Li-NH2 (1:2 equivalents, respectively) gives [{Sb(μ-NCy)}2N]3-(Li·THF)3 (LiN=NH)·0.25(dioxane) 4, in which four Li+ cations are coordinated within the trimeric cavity of the macrocyclic trianion [{Sb(μ-NCy)}2N]33-.

AB - Reaction of the Sb(III) dimer [Me2NSb(μ-NCy)]2 with Li-NH2 (1:2 equivalents, respectively) gives [{Sb(μ-NCy)}2N]3-(Li·THF)3 (LiN=NH)·0.25(dioxane) 4, in which four Li+ cations are coordinated within the trimeric cavity of the macrocyclic trianion [{Sb(μ-NCy)}2N]33-.

UR - https://www.scopus.com/pages/publications/0036008062

U2 - 10.1039/b110984g

DO - 10.1039/b110984g

M3 - Article

AN - SCOPUS:0036008062

SN - 1470-479X

SP - 481

EP - 483

JO - Dalton Transactions

JF - Dalton Transactions

IS - 4

ER -

Synthesis and structure of [{Sb(μ-NCy)}2(μ-N)]3(Li·THF)3- (LiN=NH), containing a macrocyclic [{Sb(μ-NCy)}2N]33- trianion

Abstract

Access to Document

Other files and links

Cite this

Synthesis and structure of [{Sb(μ-NCy)}₂(μ-N)]₃(Li·THF)₃- (LiN=NH), containing a macrocyclic [{Sb(μ-NCy)}₂N]₃^3- trianion