Synthesis and structure of [(MeAl(μ-PMes)(PMes))2Li4]2·7thf, containing a [MeAl(μ-PMes)(PMes)]24− tetraanion (Mes = 2,4,6-Me3C6H2)

Felipe García; Robert Haigh; Mary McPartlin; Dominic S. Wright

doi:10.1039/b305259a

Synthesis and structure of [(MeAl(μ-PMes)(PMes))₂Li₄]₂·7thf, containing a [MeAl(μ-PMes)(PMes)]₂⁴⁻ tetraanion (Mes = 2,4,6-Me₃C₆H₂)

Felipe García
, Robert Haigh
, Mary McPartlin
, Dominic S. Wright

Research output: Contribution to journal › Article › Research › peer-review

7 Citations (Scopus)

Abstract

The reaction of MeAlCl₂ with MesPHLi (1:4 equivalents) in thf/toluene gives the cage complex [(MeAl(μ-PMes)(PMes))₂Li₄]₂·7thf (1), containing an [(MeAl(μ-PMes)(PMes))₂]⁴⁻ tetraanion which is valence-isoelectronic with extensively studied Group 15 anions of the type [E(μ-NR)(NR)]₂²⁻.

Original language	English
Pages (from-to)	2052-2053
Number of pages	2
Journal	Chemical Communications
Volume	3
Issue number	16
DOIs	https://doi.org/10.1039/b305259a
Publication status	Published - 2003
Externally published	Yes

Access to Document

10.1039/b305259a

Cite this

@article{6d25e521b5cb4b589ba0d4a3d493e33f,

title = "Synthesis and structure of [(MeAl(μ-PMes)(PMes))2Li4]2·7thf, containing a [MeAl(μ-PMes)(PMes)]24− tetraanion (Mes = 2,4,6-Me3C6H2)",

abstract = "The reaction of MeAlCl2 with MesPHLi (1:4 equivalents) in thf/toluene gives the cage complex [(MeAl(μ-PMes)(PMes))2Li4]2·7thf (1), containing an [(MeAl(μ-PMes)(PMes))2]4− tetraanion which is valence-isoelectronic with extensively studied Group 15 anions of the type [E(μ-NR)(NR)]22−.",

author = "Felipe Garc{\'i}a and Robert Haigh and Mary McPartlin and Wright, \{Dominic S.\}",

year = "2003",

doi = "10.1039/b305259a",

language = "English",

volume = "3",

pages = "2052--2053",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "The Royal Society of Chemistry",

number = "16",

}

TY - JOUR

T1 - Synthesis and structure of [(MeAl(μ-PMes)(PMes))2Li4]2·7thf, containing a [MeAl(μ-PMes)(PMes)]24− tetraanion (Mes = 2,4,6-Me3C6H2)

AU - García, Felipe

AU - Haigh, Robert

AU - McPartlin, Mary

AU - Wright, Dominic S.

PY - 2003

Y1 - 2003

N2 - The reaction of MeAlCl2 with MesPHLi (1:4 equivalents) in thf/toluene gives the cage complex [(MeAl(μ-PMes)(PMes))2Li4]2·7thf (1), containing an [(MeAl(μ-PMes)(PMes))2]4− tetraanion which is valence-isoelectronic with extensively studied Group 15 anions of the type [E(μ-NR)(NR)]22−.

AB - The reaction of MeAlCl2 with MesPHLi (1:4 equivalents) in thf/toluene gives the cage complex [(MeAl(μ-PMes)(PMes))2Li4]2·7thf (1), containing an [(MeAl(μ-PMes)(PMes))2]4− tetraanion which is valence-isoelectronic with extensively studied Group 15 anions of the type [E(μ-NR)(NR)]22−.

UR - https://www.scopus.com/pages/publications/0043068097

U2 - 10.1039/b305259a

DO - 10.1039/b305259a

M3 - Article

AN - SCOPUS:0043068097

SN - 1359-7345

VL - 3

SP - 2052

EP - 2053

JO - Chemical Communications

JF - Chemical Communications

IS - 16

ER -

Synthesis and structure of [(MeAl(μ-PMes)(PMes))2Li4]2·7thf, containing a [MeAl(μ-PMes)(PMes)]24− tetraanion (Mes = 2,4,6-Me3C6H2)

Abstract

Access to Document

Other files and links

Cite this

Synthesis and structure of [(MeAl(μ-PMes)(PMes))₂Li₄]₂·7thf, containing a [MeAl(μ-PMes)(PMes)]₂⁴⁻ tetraanion (Mes = 2,4,6-Me₃C₆H₂)