Synthesis and structure of a new open metal-organic-inorganic hybrid framework [Sn(SO4)(BDC)(H2O)](BDC=terephthalic acid)

Jin Yu Sun, Ya Ming Zhou, Zhen Xia Chen, Bo Tu, Lin Hong Weng, Dong Yuan Zhao

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A new coordination polymer [Sn(SO4)(BDC)(H2O)](BDC=terephthalic acid) with two dimensional (2D) open metal-organic-inganic hybrid framework structure has solvothermally prepared in N, N-dimethylformamide solution at 160°C. The structure determined from X-ray single crystal diffraction has space group P21of monoclinic system with a=0.6816(5), b=1.7628(14), c=0.7722(6) nm, β=103.7°, V=0.9012(12) nm3, Z=4, Dc=1.569 Mg/m3; R1=0.0514[I>2σ(I)], Rw=0.1381. The product is characteristic of 2D channels with 2D wavy layer structure.

Original languageEnglish
Pages (from-to)1555-1557
Number of pages3
JournalChemical Journal of Chinese Universities
Issue number9
Publication statusPublished - 1 Sep 2003
Externally publishedYes


  • Coordination polymer
  • Metal-organic framework
  • Sn complex
  • Structure
  • Synthesis

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