A new coordination polymer [Sn(SO4)(BDC)(H2O)](BDC=terephthalic acid) with two dimensional (2D) open metal-organic-inganic hybrid framework structure has solvothermally prepared in N, N-dimethylformamide solution at 160°C. The structure determined from X-ray single crystal diffraction has space group P21of monoclinic system with a=0.6816(5), b=1.7628(14), c=0.7722(6) nm, β=103.7°, V=0.9012(12) nm3, Z=4, Dc=1.569 Mg/m3; R1=0.0514[I>2σ(I)], Rw=0.1381. The product is characteristic of 2D channels with 2D wavy layer structure.
|Number of pages||3|
|Journal||Chemical Journal of Chinese Universities|
|Publication status||Published - 1 Sep 2003|
- Coordination polymer
- Metal-organic framework
- Sn complex