Synthesis and structure of a new open metal-organic-inorganic hybrid framework [Sn(SO4)(BDC)(H2O)](BDC=terephthalic acid)

Jin Yu Sun; Ya Ming Zhou; Zhen Xia Chen; Bo Tu; Lin Hong Weng; Dong Yuan Zhao

Synthesis and structure of a new open metal-organic-inorganic hybrid framework [Sn(SO₄)(BDC)(H₂O)](BDC=terephthalic acid)

Jin Yu Sun, Ya Ming Zhou, Zhen Xia Chen, Bo Tu, Lin Hong Weng, Dong Yuan Zhao

Research output: Contribution to journal › Article › Research › peer-review

Abstract

A new coordination polymer [Sn(SO₄)(BDC)(H₂O)](BDC=terephthalic acid) with two dimensional (2D) open metal-organic-inganic hybrid framework structure has solvothermally prepared in N, N-dimethylformamide solution at 160°C. The structure determined from X-ray single crystal diffraction has space group P2₁of monoclinic system with a=0.6816(5), b=1.7628(14), c=0.7722(6) nm, β=103.7°, V=0.9012(12) nm³, Z=4, D_c=1.569 Mg/m³; R₁=0.0514[I>2σ(I)], R_w=0.1381. The product is characteristic of 2D channels with 2D wavy layer structure.

Original language	English
Pages (from-to)	1555-1557
Number of pages	3
Journal	Chemical Journal of Chinese Universities
Volume	24
Issue number	9
Publication status	Published - 1 Sep 2003
Externally published	Yes

Keywords

Coordination polymer
Metal-organic framework
Sn complex
Structure
Synthesis

Cite this

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title = "Synthesis and structure of a new open metal-organic-inorganic hybrid framework [Sn(SO4)(BDC)(H2O)](BDC=terephthalic acid)",

abstract = "A new coordination polymer [Sn(SO4)(BDC)(H2O)](BDC=terephthalic acid) with two dimensional (2D) open metal-organic-inganic hybrid framework structure has solvothermally prepared in N, N-dimethylformamide solution at 160°C. The structure determined from X-ray single crystal diffraction has space group P21of monoclinic system with a=0.6816(5), b=1.7628(14), c=0.7722(6) nm, β=103.7°, V=0.9012(12) nm3, Z=4, Dc=1.569 Mg/m3; R1=0.0514[I>2σ(I)], Rw=0.1381. The product is characteristic of 2D channels with 2D wavy layer structure.",

keywords = "Coordination polymer, Metal-organic framework, Sn complex, Structure, Synthesis",

author = "Sun, {Jin Yu} and Zhou, {Ya Ming} and Chen, {Zhen Xia} and Bo Tu and Weng, {Lin Hong} and Zhao, {Dong Yuan}",

year = "2003",

month = sep,

day = "1",

language = "English",

volume = "24",

pages = "1555--1557",

journal = "Chemical Journal of Chinese Universities",

issn = "0251-0790",

publisher = "Jilin University",

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TY - JOUR

T1 - Synthesis and structure of a new open metal-organic-inorganic hybrid framework [Sn(SO4)(BDC)(H2O)](BDC=terephthalic acid)

AU - Sun, Jin Yu

AU - Zhou, Ya Ming

AU - Chen, Zhen Xia

AU - Tu, Bo

AU - Weng, Lin Hong

AU - Zhao, Dong Yuan

PY - 2003/9/1

Y1 - 2003/9/1

N2 - A new coordination polymer [Sn(SO4)(BDC)(H2O)](BDC=terephthalic acid) with two dimensional (2D) open metal-organic-inganic hybrid framework structure has solvothermally prepared in N, N-dimethylformamide solution at 160°C. The structure determined from X-ray single crystal diffraction has space group P21of monoclinic system with a=0.6816(5), b=1.7628(14), c=0.7722(6) nm, β=103.7°, V=0.9012(12) nm3, Z=4, Dc=1.569 Mg/m3; R1=0.0514[I>2σ(I)], Rw=0.1381. The product is characteristic of 2D channels with 2D wavy layer structure.

AB - A new coordination polymer [Sn(SO4)(BDC)(H2O)](BDC=terephthalic acid) with two dimensional (2D) open metal-organic-inganic hybrid framework structure has solvothermally prepared in N, N-dimethylformamide solution at 160°C. The structure determined from X-ray single crystal diffraction has space group P21of monoclinic system with a=0.6816(5), b=1.7628(14), c=0.7722(6) nm, β=103.7°, V=0.9012(12) nm3, Z=4, Dc=1.569 Mg/m3; R1=0.0514[I>2σ(I)], Rw=0.1381. The product is characteristic of 2D channels with 2D wavy layer structure.

KW - Coordination polymer

KW - Metal-organic framework

KW - Sn complex

KW - Structure

KW - Synthesis

UR - http://www.scopus.com/inward/record.url?scp=28944453494&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:28944453494

VL - 24

SP - 1555

EP - 1557

JO - Chemical Journal of Chinese Universities

JF - Chemical Journal of Chinese Universities

SN - 0251-0790

IS - 9

ER -

Synthesis and structure of a new open metal-organic-inorganic hybrid framework [Sn(SO4)(BDC)(H2O)](BDC=terephthalic acid)

Abstract

Keywords

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Synthesis and structure of a new open metal-organic-inorganic hybrid framework [Sn(SO₄)(BDC)(H₂O)](BDC=terephthalic acid)