Synthesis and structural characterization of novel rhodium-diacylarsenido complexes

Cameron Jones, Steven J. Black, Jonathan W. Steed

Research output: Contribution to journalArticleResearchpeer-review

12 Citations (Scopus)

Abstract

The reaction of [Li{η2-OC(Mes′)AsC(Mes′)O} (OEt2)], Mes′ = C6H2Pri 3-2,4,6, with [{RhCl(COD)}2], COD = 1,5-C 8H12, in either a 1:1 or 2:1 stoichiometry yields the novel rhodium-diacylarsenido complexes, [{Rh(COD)}2-μ-Cl-μ- {As[C(O)Mes′]2}] and [Rh(COD){η1- As[C(Mes′)O]2Li(OEt2)Cl}], respectively. The X-ray crystal structure of each is described and mechanisms for their formations proposed.

Original languageEnglish
Pages (from-to)5924-5926
Number of pages3
JournalOrganometallics
Volume17
Issue number26
DOIs
Publication statusPublished - 21 Dec 1998
Externally publishedYes

Cite this