Synthesis and structural characterisation of a novel 2,3-clistibene-1,4-dione complex, [Pt(PEt3)2{η2-Bu tC(O)Sb=SbC(O)But}]

Steven J. Black; David E. Hibbs; Michael B. Hursthouse; Cameron Jones; Jonathan W. Steed

doi:10.1039/a806712k

Synthesis and structural characterisation of a novel 2,3-clistibene-1,4-dione complex, [Pt(PEt₃)₂{η²-Bu ^tC(O)Sb=SbC(O)Bu^t}]

Steven J. Black, David E. Hibbs, Michael B. Hursthouse, Cameron Jones, Jonathan W. Steed

Research output: Contribution to journal › Article › Research › peer-review

24 Citations (Scopus)

Abstract

The reaction of cis-[PtCl₂(PEt₃)₂] with 2 equiv. of [{[Li[η²-OC(Bu^t)EC(Bu^t)O)(DME) _0.5]₂}_∞], E = Sb or As, affords either the first distibene-dione complex, cis-[Pt(PEt₃)₂{η²-Bu ^tC(O)Sb=SbC(O)Bu^t}], or the related diarsenide-dione bridged complex, trans-[{Pt(PEt₃)Cl}₂{μ-η¹,η ¹-Bu^tC(O)-AsAsC(O)Bu^t}], the X-ray crystal structures of which are described.

Original language	English
Pages (from-to)	2199-2200
Number of pages	2
Journal	Chemical Communications
Issue number	20
DOIs	https://doi.org/10.1039/a806712k
Publication status	Published - 21 Oct 1998
Externally published	Yes

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title = "Synthesis and structural characterisation of a novel 2,3-clistibene-1,4-dione complex, [Pt(PEt3)2\{η2-Bu tC(O)Sb=SbC(O)But\}]",

abstract = "The reaction of cis-[PtCl2(PEt3)2] with 2 equiv. of [\{[Li[η2-OC(But)EC(But)O)(DME) 0.5]2\}∞], E = Sb or As, affords either the first distibene-dione complex, cis-[Pt(PEt3)2\{η2-Bu tC(O)Sb=SbC(O)But\}], or the related diarsenide-dione bridged complex, trans-[\{Pt(PEt3)Cl\}2\{μ-η1,η 1-ButC(O)-AsAsC(O)But\}], the X-ray crystal structures of which are described.",

author = "Black, \{Steven J.\} and Hibbs, \{David E.\} and Hursthouse, \{Michael B.\} and Cameron Jones and Steed, \{Jonathan W.\}",

year = "1998",

month = oct,

day = "21",

doi = "10.1039/a806712k",

language = "English",

pages = "2199--2200",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "The Royal Society of Chemistry",

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T1 - Synthesis and structural characterisation of a novel 2,3-clistibene-1,4-dione complex, [Pt(PEt3)2{η2-Bu tC(O)Sb=SbC(O)But}]

AU - Black, Steven J.

AU - Hibbs, David E.

AU - Hursthouse, Michael B.

AU - Jones, Cameron

AU - Steed, Jonathan W.

PY - 1998/10/21

Y1 - 1998/10/21

N2 - The reaction of cis-[PtCl2(PEt3)2] with 2 equiv. of [{[Li[η2-OC(But)EC(But)O)(DME) 0.5]2}∞], E = Sb or As, affords either the first distibene-dione complex, cis-[Pt(PEt3)2{η2-Bu tC(O)Sb=SbC(O)But}], or the related diarsenide-dione bridged complex, trans-[{Pt(PEt3)Cl}2{μ-η1,η 1-ButC(O)-AsAsC(O)But}], the X-ray crystal structures of which are described.

AB - The reaction of cis-[PtCl2(PEt3)2] with 2 equiv. of [{[Li[η2-OC(But)EC(But)O)(DME) 0.5]2}∞], E = Sb or As, affords either the first distibene-dione complex, cis-[Pt(PEt3)2{η2-Bu tC(O)Sb=SbC(O)But}], or the related diarsenide-dione bridged complex, trans-[{Pt(PEt3)Cl}2{μ-η1,η 1-ButC(O)-AsAsC(O)But}], the X-ray crystal structures of which are described.

UR - https://www.scopus.com/pages/publications/0001935692

U2 - 10.1039/a806712k

DO - 10.1039/a806712k

M3 - Article

AN - SCOPUS:0001935692

SN - 1359-7345

SP - 2199

EP - 2200

JO - Chemical Communications

JF - Chemical Communications

IS - 20

ER -

Synthesis and structural characterisation of a novel 2,3-clistibene-1,4-dione complex, [Pt(PEt3)2{η2-Bu tC(O)Sb=SbC(O)But}]

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Synthesis and structural characterisation of a novel 2,3-clistibene-1,4-dione complex, [Pt(PEt₃)₂{η²-Bu ^tC(O)Sb=SbC(O)Bu^t}]