Synthesis and metal complexes of symmetrically N-substituted bispidinones

David St C Black; Glen B. Deacon; Mick Rose

doi:10.1016/0040-4020(94)01069-C

Synthesis and metal complexes of symmetrically N-substituted bispidinones

David St C Black, Glen B. Deacon, Mick Rose

School of Chemistry

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Abstract

The symmetrically substituted bispidinones (9-23) were prepared by the Mannich reaction. The bispidinone (28) can be used to generate the diaminoethyl derivative (25) and the diphenoxy ether (32). The crystal structure of the glycinic bispidinone (20) is reported. Metal complexes of bispidinones (4), (35-54) were prepared with copper, palladium and platinum.

Original language	English
Pages (from-to)	2055-2076
Number of pages	22
Journal	Tetrahedron
Volume	51
Issue number	7
DOIs	https://doi.org/10.1016/0040-4020(94)01069-C
Publication status	Published - 13 Feb 1995

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10.1016/0040-4020(94)01069-C

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abstract = "The symmetrically substituted bispidinones (9-23) were prepared by the Mannich reaction. The bispidinone (28) can be used to generate the diaminoethyl derivative (25) and the diphenoxy ether (32). The crystal structure of the glycinic bispidinone (20) is reported. Metal complexes of bispidinones (4), (35-54) were prepared with copper, palladium and platinum.",

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AU - Deacon, Glen B.

AU - Rose, Mick

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AB - The symmetrically substituted bispidinones (9-23) were prepared by the Mannich reaction. The bispidinone (28) can be used to generate the diaminoethyl derivative (25) and the diphenoxy ether (32). The crystal structure of the glycinic bispidinone (20) is reported. Metal complexes of bispidinones (4), (35-54) were prepared with copper, palladium and platinum.

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Synthesis and metal complexes of symmetrically N-substituted bispidinones

Abstract

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