Synthesis and crystal structure of [N,N′-bis(2,3,5,6-tetrafluorophenyl)-ethane-1,2-diaminato(2-)]dipyridineplatinum(II)

G. B. Deacon; B. M. Gatehouse; I. L. Grayson; M. C. Nesbit

doi:10.1016/S0277-5387(00)88017-1

Synthesis and crystal structure of [N,N′-bis(2,3,5,6-tetrafluorophenyl)-ethane-1,2-diaminato(2-)]dipyridineplatinum(II)

G. B. Deacon, B. M. Gatehouse, I. L. Grayson, M. C. Nesbit

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

20 Citations (Scopus)

Abstract

The reaction of PtCl₂en (en = ethane-1,2-diamine) with TlO₂CC₆F₅ in boiling pyridine unexpectedly yielded a polyfluorophenyl-stabilized ethane-1,2-diaminatoplatinum(II) complex, Pt[N(p-HC₆F₄)CH₂]₂(py)₂, 1a, the structure of which has been established by X-ray crystallography.

Original language	English
Pages (from-to)	753-755
Number of pages	3
Journal	Polyhedron
Volume	3
Issue number	6
DOIs	https://doi.org/10.1016/S0277-5387(00)88017-1
Publication status	Published - 1984

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10.1016/S0277-5387(00)88017-1

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title = "Synthesis and crystal structure of [N,N′-bis(2,3,5,6-tetrafluorophenyl)-ethane-1,2-diaminato(2-)]dipyridineplatinum(II)",

abstract = "The reaction of PtCl2en (en = ethane-1,2-diamine) with TlO2CC6F5 in boiling pyridine unexpectedly yielded a polyfluorophenyl-stabilized ethane-1,2-diaminatoplatinum(II) complex, Pt[N(p-HC6F4)CH2]2(py)2, 1a, the structure of which has been established by X-ray crystallography.",

author = "Deacon, {G. B.} and Gatehouse, {B. M.} and Grayson, {I. L.} and Nesbit, {M. C.}",

year = "1984",

doi = "10.1016/S0277-5387(00)88017-1",

language = "English",

volume = "3",

pages = "753--755",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier",

number = "6",

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TY - JOUR

T1 - Synthesis and crystal structure of [N,N′-bis(2,3,5,6-tetrafluorophenyl)-ethane-1,2-diaminato(2-)]dipyridineplatinum(II)

AU - Deacon, G. B.

AU - Gatehouse, B. M.

AU - Grayson, I. L.

AU - Nesbit, M. C.

PY - 1984

Y1 - 1984

N2 - The reaction of PtCl2en (en = ethane-1,2-diamine) with TlO2CC6F5 in boiling pyridine unexpectedly yielded a polyfluorophenyl-stabilized ethane-1,2-diaminatoplatinum(II) complex, Pt[N(p-HC6F4)CH2]2(py)2, 1a, the structure of which has been established by X-ray crystallography.

AB - The reaction of PtCl2en (en = ethane-1,2-diamine) with TlO2CC6F5 in boiling pyridine unexpectedly yielded a polyfluorophenyl-stabilized ethane-1,2-diaminatoplatinum(II) complex, Pt[N(p-HC6F4)CH2]2(py)2, 1a, the structure of which has been established by X-ray crystallography.

UR - http://www.scopus.com/inward/record.url?scp=0000505437&partnerID=8YFLogxK

U2 - 10.1016/S0277-5387(00)88017-1

DO - 10.1016/S0277-5387(00)88017-1

M3 - Article

AN - SCOPUS:0000505437

VL - 3

SP - 753

EP - 755

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

IS - 6

ER -