TY - JOUR
T1 - Synthesis and crystal structure of a bulky beta-diketiminato ytterbium(II) iodide complex
AU - Jones, Cameron
AU - Nembenna, Sharanappa
AU - Stasch, Andreas
PY - 2011
Y1 - 2011
N2 - The reaction of YbI(2) with [K(THF)(3)((But)Nacnac)] ((But)Nacnac = [(DipNCBu(t))(2)CH](-); Dip = C(6)H(3)Pr (2) (i) -2,6) has afforded the dimeric complex, [ Yb(eta(5)-(But)Nacnac)(THF)(mu-I) (2)] 1. The cell parameters of compound 1 are: P-1, a = 10.498(2), b = 13.146(3), c = 16.293(3); alpha = 88.06(3), beta = 79.43(3), gamma = 71.10(3). The compound represents a rare example of a structurally characterized complex exhibiting an eta(5)-interaction between a beta-diketiminate ligand and an ytterbium(II) center
AB - The reaction of YbI(2) with [K(THF)(3)((But)Nacnac)] ((But)Nacnac = [(DipNCBu(t))(2)CH](-); Dip = C(6)H(3)Pr (2) (i) -2,6) has afforded the dimeric complex, [ Yb(eta(5)-(But)Nacnac)(THF)(mu-I) (2)] 1. The cell parameters of compound 1 are: P-1, a = 10.498(2), b = 13.146(3), c = 16.293(3); alpha = 88.06(3), beta = 79.43(3), gamma = 71.10(3). The compound represents a rare example of a structurally characterized complex exhibiting an eta(5)-interaction between a beta-diketiminate ligand and an ytterbium(II) center
UR - http://www.metapress.com.ezproxy.lib.monash.edu.au/content/m3126t485j311x70/fulltext.pdf
U2 - 10.1007/s10870-011-0128-1
DO - 10.1007/s10870-011-0128-1
M3 - Article
SN - 1074-1542
VL - 41
SP - 1490
EP - 1493
JO - Journal of Chemical Crystallography
JF - Journal of Chemical Crystallography
IS - 10
ER -