Synthesis and crystal and molecular structure of a sterically unhindered organoindium hydride compound, [Li(tmeda)2] [Me3In-H-InMe3]

David E. Hibbs; Michael B. Hursthouse; Cameron Jones; Neil A. Smithies

Synthesis and crystal and molecular structure of a sterically unhindered organoindium hydride compound, [Li(tmeda)₂] [Me₃In-H-InMe₃]

David E. Hibbs, Michael B. Hursthouse, Cameron Jones, Neil A. Smithies

Research output: Contribution to journal › Article › Research › peer-review

Abstract

The reaction of either InMe₃·Et₂O or InMe₂-Cl with a large excess of lithium hydride affords the organoindium hydride compound, [Li(tmeda)₂][Me₃In-H-InMe₃], the X-ray crystal structure of which shows the anion to have a bent hydride bridge.

Original language	English
Pages (from-to)	3108-3110
Number of pages	3
Journal	Organometallics
Volume	17
Issue number	14
Publication status	Published - 6 Jul 1998
Externally published	Yes

Cite this

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title = "Synthesis and crystal and molecular structure of a sterically unhindered organoindium hydride compound, [Li(tmeda)2] [Me3In-H-InMe3]",

abstract = "The reaction of either InMe3·Et2O or InMe2-Cl with a large excess of lithium hydride affords the organoindium hydride compound, [Li(tmeda)2][Me3In-H-InMe3], the X-ray crystal structure of which shows the anion to have a bent hydride bridge.",

author = "Hibbs, \{David E.\} and Hursthouse, \{Michael B.\} and Cameron Jones and Smithies, \{Neil A.\}",

year = "1998",

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language = "English",

volume = "17",

pages = "3108--3110",

journal = "Organometallics",

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publisher = "American Chemical Society",

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T1 - Synthesis and crystal and molecular structure of a sterically unhindered organoindium hydride compound, [Li(tmeda)2] [Me3In-H-InMe3]

AU - Hibbs, David E.

AU - Hursthouse, Michael B.

AU - Jones, Cameron

AU - Smithies, Neil A.

PY - 1998/7/6

Y1 - 1998/7/6

N2 - The reaction of either InMe3·Et2O or InMe2-Cl with a large excess of lithium hydride affords the organoindium hydride compound, [Li(tmeda)2][Me3In-H-InMe3], the X-ray crystal structure of which shows the anion to have a bent hydride bridge.

AB - The reaction of either InMe3·Et2O or InMe2-Cl with a large excess of lithium hydride affords the organoindium hydride compound, [Li(tmeda)2][Me3In-H-InMe3], the X-ray crystal structure of which shows the anion to have a bent hydride bridge.

UR - https://www.scopus.com/pages/publications/0000502791

M3 - Article

AN - SCOPUS:0000502791

SN - 0276-7333

VL - 17

SP - 3108

EP - 3110

JO - Organometallics

JF - Organometallics

IS - 14

ER -

Synthesis and crystal and molecular structure of a sterically unhindered organoindium hydride compound, [Li(tmeda)2] [Me3In-H-InMe3]

Abstract

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Cite this

Synthesis and crystal and molecular structure of a sterically unhindered organoindium hydride compound, [Li(tmeda)₂] [Me₃In-H-InMe₃]