TY - JOUR
T1 - Synthesis and characterization of mangenese(III) porphyrin supported on imidazole modified chloromethylated MIL-101(Cr)
T2 - A heterogeneous and reusable catalyst for oxidation of hydrocarbons with sodium periodate
AU - Zadehahmadi, Farnaz
AU - Tangestaninejad, Shahram
AU - Moghadam, Majid
AU - Mirkhani, Valiollah
AU - Mohammadpoor-Baltork, Iraj
AU - Khosropour, Ahmad R.
AU - Kardanpour, Reihaneh
N1 - Funding Information:
The support of this work by the Research Council of the University of Isfahan is acknowledged.
PY - 2014/10
Y1 - 2014/10
N2 - In the present work, chloromethylated MIL-101(Cr) modified with imidazole, Im-MIL-101, was applied as a support for immobilizing of tetraphenylporphyrinatomangenese(III) chloride. The imidazole-bound MIL-101, Im-MIL-101, not only used as support for immobilization of manganese porphyrin but also applied as a heterogeneous axial base. The Mn(TPP)Cl@Im-MIL-101 catalyst was characterized by UV-vis, FT-IR, X-ray diffraction (XRD), N 2 adsorption, field emission scanning electron microscopy (FE-SEM), energy dispersive X-ray (EDX), elemental analysis and inductively coupled plasma (ICP) methods. The catalytic activity of this new catalytic system was investigated in the alkene epoxidation and alkane hydroxylation using NaIO 4 as an oxidant in CH3CN/H2O at room temperature. This heterogeneous catalyst is highly efficient, stable and reusable in the oxidation of hydrocarbons.
AB - In the present work, chloromethylated MIL-101(Cr) modified with imidazole, Im-MIL-101, was applied as a support for immobilizing of tetraphenylporphyrinatomangenese(III) chloride. The imidazole-bound MIL-101, Im-MIL-101, not only used as support for immobilization of manganese porphyrin but also applied as a heterogeneous axial base. The Mn(TPP)Cl@Im-MIL-101 catalyst was characterized by UV-vis, FT-IR, X-ray diffraction (XRD), N 2 adsorption, field emission scanning electron microscopy (FE-SEM), energy dispersive X-ray (EDX), elemental analysis and inductively coupled plasma (ICP) methods. The catalytic activity of this new catalytic system was investigated in the alkene epoxidation and alkane hydroxylation using NaIO 4 as an oxidant in CH3CN/H2O at room temperature. This heterogeneous catalyst is highly efficient, stable and reusable in the oxidation of hydrocarbons.
KW - Axial ligand
KW - Manganese porphyrin
KW - Metal-organic framework
KW - MIL-101(Cr)
KW - Oxidation
UR - http://www.scopus.com/inward/record.url?scp=84903543975&partnerID=8YFLogxK
U2 - 10.1016/j.jssc.2014.05.016
DO - 10.1016/j.jssc.2014.05.016
M3 - Article
AN - SCOPUS:84903543975
SN - 0022-4596
VL - 218
SP - 56
EP - 63
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
ER -