新型三维锰(Ⅱ)配位聚合物[Mn2(NDC)2(DMF)2(H2O)]n·nDMF(NDC=2,6-萘二酸)的合成与表征

Guo Qiang Zhou; Jin Xi Chen; Zhen Xia Chen; Yun Qi Tian; Ting Yu; Lin Hong Weng; Dong Yuan Zhao

新型三维锰(Ⅱ)配位聚合物[Mn2(NDC)2(DMF)2(H2O)]n·nDMF(NDC=2,6-萘二酸)的合成与表征

Translated title of the contribution: Synthesis and Characterization of a New 3D Manganese(Ⅱ) Coordination Polymer [Mn2(NDC)2(DMF)2(H2O)]n·nDMF(NDC=2,6-Naphthalenedicarboxylate)

Guo Qiang Zhou, Jin Xi Chen, Zhen Xia Chen, Yun Qi Tian, Ting Yu, Lin Hong Weng, Dong Yuan Zhao

Research output: Contribution to journal › Article › Research › peer-review

3 Citations (Scopus)

Abstract

A new coordination polymer [Mn₂(NDC)₂(DMF) ₂(H₂O)]_n · nDMF (1) has been synthesized by the reaction of MnCl₂·4H₂O with 2, 6-naphthalenedicarboxylic acids (H₂NDC) under ambient conditions in DMF. A single crystal X-ray diffraction measurement reveals that 1 crystallized in the orthorhombic space group Pbca with a = 1.8334(2) nm, b = 1.6046(17) nm, c = 2.3706(3) nm, V = 6.974(13) nm³, Z = 8, D_c = 1.471 g/cm³, M_r = 772.50, μ = 0.790 mm^-1, F(000) = 3176, S = 0.951, (Δ/σ)_max = 0.001, Δρ _min = 0.539, Δρ_min = -0.351, R = 0.0335, wR = 0.0859. The combination of octahedral manganese (II) ions and NDC ligands leads to the formation of infinite three-dimensional (3D) networks, which have lozenge-shaped 1D channels (0.7 nm × 1.2 nm) along the crystallographic b-axis. The cavities are filled with coordinated solvent molecules (DMF) and non-coordinated ones.

Translated title of the contribution	Synthesis and Characterization of a New 3D Manganese(Ⅱ) Coordination Polymer [Mn2(NDC)2(DMF)2(H2O)]n·nDMF(NDC=2,6-Naphthalenedicarboxylate)
Original language	Chinese
Pages (from-to)	901-904
Number of pages	4
Journal	Acta Chimica Sinica
Volume	62
Issue number	9
Publication status	Published - 1 Dec 2004
Externally published	Yes

Keywords

Coordination polymer
Crystal structure
Three-dimensional network

Cite this

@article{e27a4473aea54745ad16f14b8f1a2a6c,

title = "新型三维锰(Ⅱ)配位聚合物[Mn2(NDC)2(DMF)2(H2O)]n·nDMF(NDC=2,6-萘二酸)的合成与表征",

abstract = "A new coordination polymer [Mn2(NDC)2(DMF) 2(H2O)]n · nDMF (1) has been synthesized by the reaction of MnCl2·4H2O with 2, 6-naphthalenedicarboxylic acids (H2NDC) under ambient conditions in DMF. A single crystal X-ray diffraction measurement reveals that 1 crystallized in the orthorhombic space group Pbca with a = 1.8334(2) nm, b = 1.6046(17) nm, c = 2.3706(3) nm, V = 6.974(13) nm3, Z = 8, Dc = 1.471 g/cm3, Mr = 772.50, μ = 0.790 mm-1, F(000) = 3176, S = 0.951, (Δ/σ)max = 0.001, Δρ min = 0.539, Δρmin = -0.351, R = 0.0335, wR = 0.0859. The combination of octahedral manganese (II) ions and NDC ligands leads to the formation of infinite three-dimensional (3D) networks, which have lozenge-shaped 1D channels (0.7 nm × 1.2 nm) along the crystallographic b-axis. The cavities are filled with coordinated solvent molecules (DMF) and non-coordinated ones.",

keywords = "Coordination polymer, Crystal structure, Three-dimensional network",

author = "Zhou, {Guo Qiang} and Chen, {Jin Xi} and Chen, {Zhen Xia} and Tian, {Yun Qi} and Ting Yu and Weng, {Lin Hong} and Zhao, {Dong Yuan}",

year = "2004",

month = dec,

day = "1",

language = "Chinese",

volume = "62",

pages = "901--904",

journal = "Acta Chimica Sinica",

issn = "0567-7351",

publisher = "Shanghai Institute of Organic Chemistry",

number = "9",

}

TY - JOUR

T1 - 新型三维锰(Ⅱ)配位聚合物[Mn2(NDC)2(DMF)2(H2O)]n·nDMF(NDC=2,6-萘二酸)的合成与表征

AU - Zhou, Guo Qiang

AU - Chen, Jin Xi

AU - Chen, Zhen Xia

AU - Tian, Yun Qi

AU - Yu, Ting

AU - Weng, Lin Hong

AU - Zhao, Dong Yuan

PY - 2004/12/1

Y1 - 2004/12/1

N2 - A new coordination polymer [Mn2(NDC)2(DMF) 2(H2O)]n · nDMF (1) has been synthesized by the reaction of MnCl2·4H2O with 2, 6-naphthalenedicarboxylic acids (H2NDC) under ambient conditions in DMF. A single crystal X-ray diffraction measurement reveals that 1 crystallized in the orthorhombic space group Pbca with a = 1.8334(2) nm, b = 1.6046(17) nm, c = 2.3706(3) nm, V = 6.974(13) nm3, Z = 8, Dc = 1.471 g/cm3, Mr = 772.50, μ = 0.790 mm-1, F(000) = 3176, S = 0.951, (Δ/σ)max = 0.001, Δρ min = 0.539, Δρmin = -0.351, R = 0.0335, wR = 0.0859. The combination of octahedral manganese (II) ions and NDC ligands leads to the formation of infinite three-dimensional (3D) networks, which have lozenge-shaped 1D channels (0.7 nm × 1.2 nm) along the crystallographic b-axis. The cavities are filled with coordinated solvent molecules (DMF) and non-coordinated ones.

AB - A new coordination polymer [Mn2(NDC)2(DMF) 2(H2O)]n · nDMF (1) has been synthesized by the reaction of MnCl2·4H2O with 2, 6-naphthalenedicarboxylic acids (H2NDC) under ambient conditions in DMF. A single crystal X-ray diffraction measurement reveals that 1 crystallized in the orthorhombic space group Pbca with a = 1.8334(2) nm, b = 1.6046(17) nm, c = 2.3706(3) nm, V = 6.974(13) nm3, Z = 8, Dc = 1.471 g/cm3, Mr = 772.50, μ = 0.790 mm-1, F(000) = 3176, S = 0.951, (Δ/σ)max = 0.001, Δρ min = 0.539, Δρmin = -0.351, R = 0.0335, wR = 0.0859. The combination of octahedral manganese (II) ions and NDC ligands leads to the formation of infinite three-dimensional (3D) networks, which have lozenge-shaped 1D channels (0.7 nm × 1.2 nm) along the crystallographic b-axis. The cavities are filled with coordinated solvent molecules (DMF) and non-coordinated ones.

KW - Coordination polymer

KW - Crystal structure

KW - Three-dimensional network

UR - http://www.scopus.com/inward/record.url?scp=33749122326&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:33749122326

VL - 62

SP - 901

EP - 904

JO - Acta Chimica Sinica

JF - Acta Chimica Sinica

SN - 0567-7351

IS - 9

ER -

新型三维锰(Ⅱ)配位聚合物[Mn2(NDC)2(DMF)2(H2O)]n·nDMF(NDC=2,6-萘二酸)的合成与表征

Abstract

Keywords

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