Synthesis and characterisation of zinc gallyl complexes: First structural elucidations of Zn-Ga bonds

Cameron Jones; Richard Rose; Andreas Stasch

doi:10.1039/b706402k

Synthesis and characterisation of zinc gallyl complexes: First structural elucidations of Zn-Ga bonds

Cameron Jones, Richard Rose, Andreas Stasch

School of Chemistry

Research output: Contribution to journal › Comment / Debate › Research › peer-review

44 Citations (Scopus)

Abstract

Reactions of the anionic gallium(i) heterocycle, [:Ga([N(Ar)C(H)]₂)]⁻ (Ar = C₆H₃Prⁱ₂-2,6), with two N, N-chelated zinc chloride complexes have yielded the compounds, [(Prⁱ₂NC[N(Ar)]₂)ZnGa([N(Ar)C(H)]₂)] and [(tmeda)Zn(Ga([N(Ar)C(H)]₂))₂] which contain the first crystallographically characterised Zn-Ga bonds.

Original language	English
Pages (from-to)	2997-2999
Number of pages	3
Journal	Dalton Transactions
Issue number	28
DOIs	https://doi.org/10.1039/b706402k
Publication status	Published - 14 Jun 2007

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title = "Synthesis and characterisation of zinc gallyl complexes: First structural elucidations of Zn-Ga bonds",

abstract = "Reactions of the anionic gallium(i) heterocycle, [:Ga([N(Ar)C(H)]2)]− (Ar = C6H3Pri2-2,6), with two N, N-chelated zinc chloride complexes have yielded the compounds, [(Pri2NC[N(Ar)]2)ZnGa([N(Ar)C(H)]2)] and [(tmeda)Zn(Ga([N(Ar)C(H)]2))2] which contain the first crystallographically characterised Zn-Ga bonds.",

author = "Cameron Jones and Richard Rose and Andreas Stasch",

year = "2007",

month = jun,

day = "14",

doi = "10.1039/b706402k",

language = "English",

pages = "2997--2999",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "The Royal Society of Chemistry",

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T1 - Synthesis and characterisation of zinc gallyl complexes

T2 - First structural elucidations of Zn-Ga bonds

AU - Jones, Cameron

AU - Rose, Richard

AU - Stasch, Andreas

PY - 2007/6/14

Y1 - 2007/6/14

N2 - Reactions of the anionic gallium(i) heterocycle, [:Ga([N(Ar)C(H)]2)]− (Ar = C6H3Pri2-2,6), with two N, N-chelated zinc chloride complexes have yielded the compounds, [(Pri2NC[N(Ar)]2)ZnGa([N(Ar)C(H)]2)] and [(tmeda)Zn(Ga([N(Ar)C(H)]2))2] which contain the first crystallographically characterised Zn-Ga bonds.

AB - Reactions of the anionic gallium(i) heterocycle, [:Ga([N(Ar)C(H)]2)]− (Ar = C6H3Pri2-2,6), with two N, N-chelated zinc chloride complexes have yielded the compounds, [(Pri2NC[N(Ar)]2)ZnGa([N(Ar)C(H)]2)] and [(tmeda)Zn(Ga([N(Ar)C(H)]2))2] which contain the first crystallographically characterised Zn-Ga bonds.

UR - http://www.scopus.com/inward/record.url?scp=85034312574&partnerID=8YFLogxK

U2 - 10.1039/b706402k

DO - 10.1039/b706402k

M3 - Comment / Debate

SP - 2997

EP - 2999

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 28

ER -

Synthesis and characterisation of zinc gallyl complexes: First structural elucidations of Zn-Ga bonds

Abstract

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