Synthesis and characterisation of heterobimetallic lanthanoid O-based cluster/cages

Philip Craig Andrews, Guillaume Bousrez, P C Junk, Dominique Tobias Thielemann, Melissa V. Werrett

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2 Citations (Scopus)

Abstract

We report the syntheses of new mono- and bimetallic lanthanoid compounds. The metal ratio of tetra- and penta-nuclear clusters are determined by Energy Dispersive X-ray Spectroscopy (EDS). The results show, for an equal proportion of lanthanide salts introduced, different metal ratios are achieved for the clusters. This ratio appears to be dependent on the size and electronic density of the metals. Studies realized the best conditions to achieve a 1:1 metal ratio.
Original languageEnglish
Pages (from-to)679-684
Number of pages6
JournalEuropean Journal of Inorganic Chemistry
Volume2017
Issue number3
DOIs
Publication statusPublished - Jan 2017

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