Syntheses, solution and solid state 13P{1H} NMR studies, of the first symmetrically-bridging μ-perpendicular phosphaalkyne dirhodium(I) complexes [Rh2X2(μ-dppm) 2(μ-RCP)] (R tBu, Ad; X Cl or Br)

Saud I. Al-Resayes; Cameron Jones; Mohd Jamil Maah; John F. Nixon

doi:10.1016/0022-328X(94)80037-5

Syntheses, solution and solid state ¹³P{¹H} NMR studies, of the first symmetrically-bridging μ-perpendicular phosphaalkyne dirhodium(I) complexes [Rh₂X₂(μ-dppm) ₂(μ-RCP)] (R ^tBu, Ad; X Cl or Br)

Saud I. Al-Resayes
, Cameron Jones
, Mohd Jamil Maah
, John F. Nixon

Research output: Contribution to journal › Article › Research › peer-review

2 Citations (Scopus)

Abstract

The first examples of symmetrically bridging μ-perpendicular phosphaalkyne complexes are reported. Their structures have been established by solution and solid state ³¹P{¹H} NMR spectroscopy.

Original language	English
Pages (from-to)	107-111
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	468
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(94)80037-5
Publication status	Published - 5 Apr 1994
Externally published	Yes

Keywords

Alkyne
Nuclear magnetic resonance
Phosphorus
Rhodium

Access to Document

10.1016/0022-328X(94)80037-5

Cite this

@article{95b4c38af80941ebb190434529224550,

title = "Syntheses, solution and solid state 13P\{1H\} NMR studies, of the first symmetrically-bridging μ-perpendicular phosphaalkyne dirhodium(I) complexes [Rh2X2(μ-dppm) 2(μ-RCP)] (R tBu, Ad; X Cl or Br)",

abstract = "The first examples of symmetrically bridging μ-perpendicular phosphaalkyne complexes are reported. Their structures have been established by solution and solid state 31P\{1H\} NMR spectroscopy.",

keywords = "Alkyne, Nuclear magnetic resonance, Phosphorus, Rhodium",

author = "Al-Resayes, \{Saud I.\} and Cameron Jones and Maah, \{Mohd Jamil\} and Nixon, \{John F.\}",

year = "1994",

month = apr,

day = "5",

doi = "10.1016/0022-328X(94)80037-5",

language = "English",

volume = "468",

pages = "107--111",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier BV",

number = "1-2",

}

Syntheses, solution and solid state ¹³P{¹H} NMR studies, of the first symmetrically-bridging μ-perpendicular phosphaalkyne dirhodium(I) complexes [Rh₂X₂(μ-dppm) ₂(μ-RCP)] (R ^tBu, Ad; X Cl or Br). / Al-Resayes, Saud I.; Jones, Cameron; Maah, Mohd Jamil et al.
In: Journal of Organometallic Chemistry, Vol. 468, No. 1-2, 05.04.1994, p. 107-111.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Syntheses, solution and solid state 13P{1H} NMR studies, of the first symmetrically-bridging μ-perpendicular phosphaalkyne dirhodium(I) complexes [Rh2X2(μ-dppm) 2(μ-RCP)] (R tBu, Ad; X Cl or Br)

AU - Al-Resayes, Saud I.

AU - Jones, Cameron

AU - Maah, Mohd Jamil

AU - Nixon, John F.

PY - 1994/4/5

Y1 - 1994/4/5

N2 - The first examples of symmetrically bridging μ-perpendicular phosphaalkyne complexes are reported. Their structures have been established by solution and solid state 31P{1H} NMR spectroscopy.

AB - The first examples of symmetrically bridging μ-perpendicular phosphaalkyne complexes are reported. Their structures have been established by solution and solid state 31P{1H} NMR spectroscopy.

KW - Alkyne

KW - Nuclear magnetic resonance

KW - Phosphorus

KW - Rhodium

UR - https://www.scopus.com/pages/publications/15444380315

U2 - 10.1016/0022-328X(94)80037-5

DO - 10.1016/0022-328X(94)80037-5

M3 - Article

AN - SCOPUS:15444380315

SN - 0022-328X

VL - 468

SP - 107

EP - 111

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2