Syntheses, solution and solid state 13P{1H} NMR studies, of the first symmetrically-bridging μ-perpendicular phosphaalkyne dirhodium(I) complexes [Rh2X2(μ-dppm) 2(μ-RCP)] (R tBu, Ad; X Cl or Br)

Saud I. Al-Resayes, Cameron Jones, Mohd Jamil Maah, John F. Nixon

Research output: Contribution to journalArticleResearchpeer-review

2 Citations (Scopus)

Abstract

The first examples of symmetrically bridging μ-perpendicular phosphaalkyne complexes are reported. Their structures have been established by solution and solid state 31P{1H} NMR spectroscopy.

Original languageEnglish
Pages (from-to)107-111
Number of pages5
JournalJournal of Organometallic Chemistry
Volume468
Issue number1-2
DOIs
Publication statusPublished - 5 Apr 1994
Externally publishedYes

Keywords

  • Alkyne
  • Nuclear magnetic resonance
  • Phosphorus
  • Rhodium

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