Syntheses and anion binding capabilities of bis(diarylboryl) ferrocenes and related systems

Michael J. Kelly; Alexander E.J. Broomsgrove; Ian R. Morgan; Inke Siewert; Philip Fitzpatrick; Jessica Smart; Dragoslav Vidovic; Simon Aldridge

doi:10.1021/om400152x

Syntheses and anion binding capabilities of bis(diarylboryl) ferrocenes and related systems

Michael J. Kelly, Alexander E.J. Broomsgrove, Ian R. Morgan, Inke Siewert, Philip Fitzpatrick, Jessica Smart, Dragoslav Vidovic, Simon Aldridge

Research output: Contribution to journal › Article › Research › peer-review

20 Citations (Scopus)

Abstract

Isomeric diborylated ferrocenes featuring 1,1′-, 1,2-, and 1,3-substitution patterns have been targeted via a combination of electrophilic aromatic substitution and directed ortho-lithiation protocols. While none of these systems are competent for the Lewis acid chelation of fluoride, related systems featuring a mixed B/Si acceptor set capture 1 equiv of fluoride via a Si-F-B bridging motif.

Original language	English
Pages (from-to)	2674-2684
Number of pages	11
Journal	Organometallics
Volume	32
Issue number	9
DOIs	https://doi.org/10.1021/om400152x
Publication status	Published - 13 May 2013
Externally published	Yes

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abstract = "Isomeric diborylated ferrocenes featuring 1,1′-, 1,2-, and 1,3-substitution patterns have been targeted via a combination of electrophilic aromatic substitution and directed ortho-lithiation protocols. While none of these systems are competent for the Lewis acid chelation of fluoride, related systems featuring a mixed B/Si acceptor set capture 1 equiv of fluoride via a Si-F-B bridging motif.",

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AU - Siewert, Inke

AU - Fitzpatrick, Philip

AU - Smart, Jessica

AU - Vidovic, Dragoslav

AU - Aldridge, Simon

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AB - Isomeric diborylated ferrocenes featuring 1,1′-, 1,2-, and 1,3-substitution patterns have been targeted via a combination of electrophilic aromatic substitution and directed ortho-lithiation protocols. While none of these systems are competent for the Lewis acid chelation of fluoride, related systems featuring a mixed B/Si acceptor set capture 1 equiv of fluoride via a Si-F-B bridging motif.

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Syntheses and anion binding capabilities of bis(diarylboryl) ferrocenes and related systems

Abstract

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