Syntheses and anion binding capabilities of bis(diarylboryl) ferrocenes and related systems

Michael J. Kelly, Alexander E.J. Broomsgrove, Ian R. Morgan, Inke Siewert, Philip Fitzpatrick, Jessica Smart, Dragoslav Vidovic, Simon Aldridge

Research output: Contribution to journalArticleResearchpeer-review

19 Citations (Scopus)

Abstract

Isomeric diborylated ferrocenes featuring 1,1′-, 1,2-, and 1,3-substitution patterns have been targeted via a combination of electrophilic aromatic substitution and directed ortho-lithiation protocols. While none of these systems are competent for the Lewis acid chelation of fluoride, related systems featuring a mixed B/Si acceptor set capture 1 equiv of fluoride via a Si-F-B bridging motif.

Original languageEnglish
Pages (from-to)2674-2684
Number of pages11
JournalOrganometallics
Volume32
Issue number9
DOIs
Publication statusPublished - 13 May 2013
Externally publishedYes

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