Symmetry breaking above room temperature in an Fe(II) spin crossover complex with an N4O2 donor set

Wasinee Phonsri; Casey G. Davies; Guy N L Jameson; Boujemaa Moubaraki; Jas S. Ward; Paul Eric Kruger; Guillaume Chastanet; Keith Murray

doi:10.1039/c6cc10040f

Symmetry breaking above room temperature in an Fe(II) spin crossover complex with an N₄O₂ donor set

Wasinee Phonsri, Casey G. Davies, Guy N L Jameson, Boujemaa Moubaraki, Jas S. Ward, Paul Eric Kruger, Guillaume Chastanet, Keith Murray

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

26 Citations (Scopus)

Abstract

[Fe(qsal-Cl)₂] is one of the few known Fe(ii) spin crossover compounds with an N₄O₂ donor atom environment. It shows an abrupt two-step spin transition at 308 and 316 K and importantly, symmetry breaking at the highest temperature reported, to date, in spin crossover compounds.

Original language	English
Pages (from-to)	1374-1377
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	8
DOIs	https://doi.org/10.1039/c6cc10040f
Publication status	Published - 2017

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10.1039/c6cc10040f

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Cite this

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title = "Symmetry breaking above room temperature in an Fe(II) spin crossover complex with an N4O2 donor set",

abstract = "[Fe(qsal-Cl)2] is one of the few known Fe(ii) spin crossover compounds with an N4O2 donor atom environment. It shows an abrupt two-step spin transition at 308 and 316 K and importantly, symmetry breaking at the highest temperature reported, to date, in spin crossover compounds.",

author = "Wasinee Phonsri and Davies, {Casey G.} and Jameson, {Guy N L} and Boujemaa Moubaraki and Ward, {Jas S.} and Kruger, {Paul Eric} and Guillaume Chastanet and Keith Murray",

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doi = "10.1039/c6cc10040f",

language = "English",

volume = "53",

pages = "1374--1377",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "The Royal Society of Chemistry",

number = "8",

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Symmetry breaking above room temperature in an Fe(II) spin crossover complex with an N₄O₂ donor set. / Phonsri, Wasinee; Davies, Casey G.; Jameson, Guy N L; Moubaraki, Boujemaa; Ward, Jas S.; Kruger, Paul Eric; Chastanet, Guillaume; Murray, Keith.

In: Chemical Communications, Vol. 53, No. 8, 2017, p. 1374-1377.

Research output: Contribution to journal › Article › Research › peer-review

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T1 - Symmetry breaking above room temperature in an Fe(II) spin crossover complex with an N4O2 donor set

AU - Phonsri, Wasinee

AU - Davies, Casey G.

AU - Jameson, Guy N L

AU - Moubaraki, Boujemaa

AU - Ward, Jas S.

AU - Kruger, Paul Eric

AU - Chastanet, Guillaume

AU - Murray, Keith

PY - 2017

Y1 - 2017

N2 - [Fe(qsal-Cl)2] is one of the few known Fe(ii) spin crossover compounds with an N4O2 donor atom environment. It shows an abrupt two-step spin transition at 308 and 316 K and importantly, symmetry breaking at the highest temperature reported, to date, in spin crossover compounds.

AB - [Fe(qsal-Cl)2] is one of the few known Fe(ii) spin crossover compounds with an N4O2 donor atom environment. It shows an abrupt two-step spin transition at 308 and 316 K and importantly, symmetry breaking at the highest temperature reported, to date, in spin crossover compounds.

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DO - 10.1039/c6cc10040f

M3 - Article

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VL - 53

SP - 1374

EP - 1377

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 8

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