Surface plasmon resonances in strongly coupled gold nanosphere chains from monomer to hexamer

Steven Barrow, Alison Funston, Daniel Gomez, Tim Davis, Paul Mulvaney

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Abstract

We present experimental data on the light scattering properties of linear chains of gold nanoparticles with up to six nanoparticles and an interparticle spacing of 1 nm. A red shift of the surface plasmon resonance with increasing chain length is observed. An exponential model applied to the experimental data allows determination of an asymptotic maximum resonance at a chain length of 10-12 particles. The optical data are compared with analytical and numerical calculation methods (EEM and BEM).
Original languageEnglish
Pages (from-to)4180 - 4187
Number of pages8
JournalNano Letters
Volume11
Issue number10
DOIs
Publication statusPublished - 2011

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