TY - JOUR
T1 - Supramolecular architecture of silver(I) coordination polymers containing polydentate N-donor ligands
AU - Chainok, Kittipong
AU - Neville, Suzanne M
AU - Forsyth, Craig Macdonald
AU - Gee, William James
AU - Murray, Keith Spencer
AU - Batten, Stuart Robert
PY - 2012
Y1 - 2012
N2 - The reaction of the polydentate N-donor ligands bmtz, H(2)bmtz, and bptz with various silver salts was investigated. New 1D coordination polymers [Ag-2(bmtz) (ClO4)]ClO4 (1), [Ag(bmtz)]ClO4 center dot MeCN (2), [ Ag(tcm) (2)(H(2)bmtz)(MeCN)] (3) and [Ag(bptz)(NO3)] (5), and 2-D sheet structures, [ Ag(tcm) (2)bmtz] (4), were synthesized. The structures are built up through the combination of coordination bonds, hydrogen bonding, Ag-pi, pi-pi, and anion-pi interactions to generate new supramolecular architectures. The supramolecular structure of the protonated amine salt [H(2)bptz](NO3)(2) (6) is also described.
AB - The reaction of the polydentate N-donor ligands bmtz, H(2)bmtz, and bptz with various silver salts was investigated. New 1D coordination polymers [Ag-2(bmtz) (ClO4)]ClO4 (1), [Ag(bmtz)]ClO4 center dot MeCN (2), [ Ag(tcm) (2)(H(2)bmtz)(MeCN)] (3) and [Ag(bptz)(NO3)] (5), and 2-D sheet structures, [ Ag(tcm) (2)bmtz] (4), were synthesized. The structures are built up through the combination of coordination bonds, hydrogen bonding, Ag-pi, pi-pi, and anion-pi interactions to generate new supramolecular architectures. The supramolecular structure of the protonated amine salt [H(2)bptz](NO3)(2) (6) is also described.
UR - http://pubs.rsc.org/en/content/articlepdf/2012/ce/c2ce25225b?page=search
U2 - 10.1039/c2ce25225b
DO - 10.1039/c2ce25225b
M3 - Article
SN - 1466-8033
VL - 14
SP - 3717
EP - 3726
JO - CrystEngComm
JF - CrystEngComm
IS - 10
ER -