Supramolecular architecture containing end-capping bis-imidazolium cations

Irene Ling, Yatimah Alias, Alexandre N. Sobolev, Lindsay T. Byrne, Colin L. Raston

Research output: Contribution to journalArticleResearchpeer-review

15 Citations (Scopus)

Abstract

Multi-component self-assembly involving bis-phosphonium and bis-imidazolium cations, and p-sulfonatocalix[4]arene feature supermolecules based on two geometrically opposed calixarenes end-capping each bis-imidazolium cation, either with coordinated lanthanide cations or with the phosphonium cations residing around the upper rim of the calixarenes. The nature of the calixarene-bis-imidazolium interaction is mapped out using Hirshfeld surface analysis. 1H NMR and ROESY experiments establish the formation of the supermolecules of the bis-imidazolium cation and calixarenes in solution.

Original languageEnglish
Pages (from-to)787-793
Number of pages7
JournalCrystEngComm
Volume13
Issue number3
DOIs
Publication statusPublished - 7 Feb 2011
Externally publishedYes

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