Superwettability-induced confined reaction toward high-performance flexible electrodes

Weiwei Xiong, Hongliang Liu, Yahong Zhou, Yi Ding, Xiqi Zhang, Lei Jiang

Research output: Contribution to journalArticleResearchpeer-review

8 Citations (Scopus)

Abstract

To find a general strategy to realize confinement of the conductive layer for high-performance flexible electrodes, with improved interfacial adhesion and high conductivity, is of important scientific significance. In this work, superwettability-induced confined reaction is used to fabricate high-performance flexible Ag/polymer electrodes, showing significantly improved silver conversion efficiency and interfacial adhesion. The as-prepared flexible electrodes by superhydrophilic polymeric surface under oil are highly conductive with an order of magnitude higher than the Ag/polymer electrodes obtained from original polymeric surface. The high conductivity achieved via superhydrophilic confinement is ascribed to the fact that the superhydrophilic polymeric surface can enhance the reaction rate of silver deposition and reduce the size of silver nanoparticles to achieve the densest packing. This new approach will provide a simple method to fabricate flexible and highly conductive Ag/polymer electrodes with excellent adhesion between the conductive layer and the substrate, and can be extended to other metal/polymeric electrodes or alloy/polymeric electrodes.

Original languageEnglish
Pages (from-to)12534-12540
Number of pages7
JournalACS Applied Materials & Interfaces
Volume8
Issue number19
DOIs
Publication statusPublished - 18 May 2016
Externally publishedYes

Keywords

  • conductivity
  • confinement
  • flexible electrode
  • interfacial adhesion
  • superwettability

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