Superhydrophobicity-mediated electrochemical reaction along the solid-liquid-gas triphase interface: edge-growth of gold architectures

Yuchen Wu, Kesong Liu, Bin Su, Lei Jiang

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36 Citations (Scopus)


A superhydrophobic pillar‐structured electrode leads to uncommon electrochemical behavior. The anti‐wetting reaction surface restricts the contact between electrolyte and electrode to the pillar tops, as a result of trapped air pockets in the gaps between pillars. The electrochemical reaction occurs mainly at the solid/liquid/gas triphase interface, instead of the traditional solid/liquid diphase surface, yielding unique edge‐growth structures — for example gold microflowers — on the top of each pillar.
Original languageEnglish
Pages (from-to)1124-1128
Number of pages5
JournalAdvanced Materials
Issue number7
Publication statusPublished - 14 Feb 2014
Externally publishedYes

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