19F NMR evidence for multiple fluoride ion sites in heavy metal fluoride glasses

D. R. MacFarlane; J. O. Browne; T. J. Bastow; G. W. West

doi:10.1016/0022-3093(89)90298-6

¹⁹F NMR evidence for multiple fluoride ion sites in heavy metal fluoride glasses

D. R. MacFarlane, J. O. Browne, T. J. Bastow, G. W. West

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

16 Citations (Scopus)

Abstract

A ¹⁹F NMR study of a typical heavy metal fluoride glass has revealed the presence of three discrete fluoride ion sites in the glass structure. Line shape analysis suggests that one of these sites plays a role in the structural framework while the other types of fluoride ion become mobile with increasing temperature.

Original language	English
Pages (from-to)	289-293
Number of pages	5
Journal	Journal of Non-Crystalline Solids
Volume	108
Issue number	3
DOIs	https://doi.org/10.1016/0022-3093(89)90298-6
Publication status	Published - 1 Jan 1989

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10.1016/0022-3093(89)90298-6

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title = "19F NMR evidence for multiple fluoride ion sites in heavy metal fluoride glasses",

abstract = "A 19F NMR study of a typical heavy metal fluoride glass has revealed the presence of three discrete fluoride ion sites in the glass structure. Line shape analysis suggests that one of these sites plays a role in the structural framework while the other types of fluoride ion become mobile with increasing temperature.",

author = "MacFarlane, {D. R.} and Browne, {J. O.} and Bastow, {T. J.} and West, {G. W.}",

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AB - A 19F NMR study of a typical heavy metal fluoride glass has revealed the presence of three discrete fluoride ion sites in the glass structure. Line shape analysis suggests that one of these sites plays a role in the structural framework while the other types of fluoride ion become mobile with increasing temperature.

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19F NMR evidence for multiple fluoride ion sites in heavy metal fluoride glasses

Abstract

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¹⁹F NMR evidence for multiple fluoride ion sites in heavy metal fluoride glasses