Structural variation involving triphenylbenzylphosphonium cation and p-sulfonated calixarene anion

Irene Ling; Alexandre N. Sobolev

doi:10.1016/j.matpr.2018.08.060

Structural variation involving triphenylbenzylphosphonium cation and p-sulfonated calixarene anion

Irene Ling
, Alexandre N. Sobolev

Malaysia Sch of Science

Research output: Chapter in Book/Report/Conference proceeding › Conference Paper › Other

Abstract

Combining equimolar of p-sulfonated calix[4]arene anion and triphenylbenzylphosphonium cation along with three molar of gadolinium(III) ions affords the typical bilayer arrangement while incorporating the same phosphonium cation in excess amount induces a porous-like array in the extended structure however without the uptake of the lanthanide in the final product. Addition of butyl-methylpyrrolidinium cation as a guest molecule demonstrates consistency to recent findings where the charged molecule is selectively drawn into the cavity with the long alkyl chain directs away from the cavity.

Original language	English
Title of host publication	7th Asian Conference on Colloid and Interface Science
Publisher	Elsevier
Pages	S166-S171
Number of pages	6
Volume	5
Edition	Supplement 2
DOIs	https://doi.org/10.1016/j.matpr.2018.08.060
Publication status	Published - 2018
Event	Asian Conference on Colloid and Interface Science, 2017 - Kuala Lumpur, Malaysia Duration: 8 Aug 2017 → 11 Aug 2017 Conference number: 7th

Publication series

Name	Materials Today Proceedings
Publisher	Elsevier
Number	Supplement 2
Volume	5
ISSN (Print)	2214-7853

Conference

Conference	Asian Conference on Colloid and Interface Science, 2017
Abbreviated title	ACCIS 2017
Country/Territory	Malaysia
City	Kuala Lumpur
Period	8/08/17 → 11/08/17

Keywords

calixarene
crystallography
lanthanide
phosphonium
self-assembly

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10.1016/j.matpr.2018.08.060Licence: CC BY

338519544-oaFinal published version, 1.54 MBLicence: CC BY

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title = "Structural variation involving triphenylbenzylphosphonium cation and p-sulfonated calixarene anion",

abstract = "Combining equimolar of p-sulfonated calix[4]arene anion and triphenylbenzylphosphonium cation along with three molar of gadolinium(III) ions affords the typical bilayer arrangement while incorporating the same phosphonium cation in excess amount induces a porous-like array in the extended structure however without the uptake of the lanthanide in the final product. Addition of butyl-methylpyrrolidinium cation as a guest molecule demonstrates consistency to recent findings where the charged molecule is selectively drawn into the cavity with the long alkyl chain directs away from the cavity.",

keywords = "calixarene, crystallography, lanthanide, phosphonium, self-assembly",

author = "Irene Ling and Sobolev, \{Alexandre N.\}",

year = "2018",

doi = "10.1016/j.matpr.2018.08.060",

language = "English",

volume = "5",

series = "Materials Today Proceedings",

publisher = "Elsevier",

number = "Supplement 2",

pages = "S166--S171",

booktitle = "7th Asian Conference on Colloid and Interface Science",

address = "Netherlands",

edition = "Supplement 2",

note = "Asian Conference on Colloid and Interface Science, 2017, ACCIS 2017 ; Conference date: 08-08-2017 Through 11-08-2017",

}

Ling, I & Sobolev, AN 2018, Structural variation involving triphenylbenzylphosphonium cation and p-sulfonated calixarene anion. in 7th Asian Conference on Colloid and Interface Science. Supplement 2 edn, vol. 5, Materials Today Proceedings, no. Supplement 2, vol. 5, Elsevier, pp. S166-S171, Asian Conference on Colloid and Interface Science, 2017, Kuala Lumpur, Malaysia, 8/08/17. https://doi.org/10.1016/j.matpr.2018.08.060

Structural variation involving triphenylbenzylphosphonium cation and p-sulfonated calixarene anion. / Ling, Irene; Sobolev, Alexandre N.
7th Asian Conference on Colloid and Interface Science. Vol. 5 Supplement 2. ed. Elsevier, 2018. p. S166-S171 (Materials Today Proceedings; Vol. 5, No. Supplement 2).

Research output: Chapter in Book/Report/Conference proceeding › Conference Paper › Other

TY - GEN

T1 - Structural variation involving triphenylbenzylphosphonium cation and p-sulfonated calixarene anion

AU - Ling, Irene

AU - Sobolev, Alexandre N.

N1 - Conference code: 7th

PY - 2018

Y1 - 2018

N2 - Combining equimolar of p-sulfonated calix[4]arene anion and triphenylbenzylphosphonium cation along with three molar of gadolinium(III) ions affords the typical bilayer arrangement while incorporating the same phosphonium cation in excess amount induces a porous-like array in the extended structure however without the uptake of the lanthanide in the final product. Addition of butyl-methylpyrrolidinium cation as a guest molecule demonstrates consistency to recent findings where the charged molecule is selectively drawn into the cavity with the long alkyl chain directs away from the cavity.

AB - Combining equimolar of p-sulfonated calix[4]arene anion and triphenylbenzylphosphonium cation along with three molar of gadolinium(III) ions affords the typical bilayer arrangement while incorporating the same phosphonium cation in excess amount induces a porous-like array in the extended structure however without the uptake of the lanthanide in the final product. Addition of butyl-methylpyrrolidinium cation as a guest molecule demonstrates consistency to recent findings where the charged molecule is selectively drawn into the cavity with the long alkyl chain directs away from the cavity.

KW - calixarene

KW - crystallography

KW - lanthanide

KW - phosphonium

KW - self-assembly

UR - https://www.scopus.com/pages/publications/85062497440

U2 - 10.1016/j.matpr.2018.08.060

DO - 10.1016/j.matpr.2018.08.060

M3 - Conference Paper

AN - SCOPUS:85062497440

VL - 5

T3 - Materials Today Proceedings

SP - S166-S171

BT - 7th Asian Conference on Colloid and Interface Science

PB - Elsevier

T2 - Asian Conference on Colloid and Interface Science, 2017

Y2 - 8 August 2017 through 11 August 2017

ER -

Structural variation involving triphenylbenzylphosphonium cation and p-sulfonated calixarene anion

Abstract

Publication series

Conference

Keywords

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