TY - JOUR
T1 - Structural systematics for lanthanide(III) systems
T2 - Interactions of the achiral hexamminecobalt(III) cation with tris(dipicolinato)lanthanate(III) anions
AU - Harrowfield, Jack M.
AU - Ling, Irene
AU - Skelton, Brian W.
AU - Sobolev, Alexandre N.
AU - White, Allan H.
PY - 2017
Y1 - 2017
N2 - Extended structural studies, largely determinations at ∼150K, of the family of hydrates of [Co(NH3)6][Ln(dipic)3] (Ln=La-Lu, and Y; dipic=dipicolinate=pyridine-2,6-dicarboxylate) have provided detailed evidence of the nature of the interactions between the formally achiral cation and the chiral anions. They also provide a reference point for consideration of related systems incorporating chiral cations with and without the capacity to act as H-bond donors.
AB - Extended structural studies, largely determinations at ∼150K, of the family of hydrates of [Co(NH3)6][Ln(dipic)3] (Ln=La-Lu, and Y; dipic=dipicolinate=pyridine-2,6-dicarboxylate) have provided detailed evidence of the nature of the interactions between the formally achiral cation and the chiral anions. They also provide a reference point for consideration of related systems incorporating chiral cations with and without the capacity to act as H-bond donors.
UR - https://www.scopus.com/pages/publications/85018355165
U2 - 10.1071/CH16584
DO - 10.1071/CH16584
M3 - Article
AN - SCOPUS:85018355165
SN - 0004-9425
VL - 70
SP - 485
EP - 493
JO - Australian Journal of Chemistry
JF - Australian Journal of Chemistry
IS - 5
ER -