Projects per year
Abstract
We have prepared the new aminophosphine Ph2PNHMes 2 [Mes = mesityl (2,4,6-Me3C6H2)], and the aminoiminophosphorane Ph2P(=NMes)NHMes 4 (MesLH), and obtained the new alkali metal complexes [(DipLLi)2] 5 [DipL = Ph2P(NDip)2, Dip = 2,6-iPr2C6H3], [(MesLLi)2] 6, [(DipL)(DipN2L)Li2] 7 [DipN2L = Ph2P(NDip)(N3Dip)], [(DipN2L)2Li2] 8, [DipLLi(THF)] 9, [DipLLi(THF)2] 10, [(DipLNa)2] 11, [(MesLNa)n] 12, [DipLNa(THF)2] 13, [{MesLNa(THF)}2] 14 and [MesLK] 16 by deprotonation of their respective ligand precursors with standard strong alkali metal bases in various solvents. The crystal structures of 2, 4–6, 7·8, 9–14, and 16 are reported. The different coordination modes in their solid-state structures are discussed and generally compared to the solution behavior of those species
Original language | English |
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Pages (from-to) | 258-270 |
Number of pages | 13 |
Journal | European Journal of Inorganic Chemistry |
Volume | 2015 |
Issue number | 2 |
DOIs | |
Publication status | Published - 2015 |
Keywords
- Alkali metals
- Chelates
- Phosphanes
- Ligand design
- Steric hindrance
Projects
- 1 Finished
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New reactivity from unusual main group compounds
Stasch, A.
Australian Research Council (ARC), Monash University
29/03/12 → 31/03/16
Project: Research