Stress corrosion cracking and corrosion fatigue characterisation of MgZn1Ca0.3 (ZX10) in a simulated physiological environment

Sajjad Jafari, R. K. Singh Raman, Chris H.J. Davies, Joelle Hofstetter, Peter J Uggowitzer, Jörg F. Löffler

Research output: Contribution to journalArticleResearchpeer-review

Abstract

Magnesium (Mg) alloys have attracted great attention as potential materials for biodegradable implants. It is essential that an implant material possesses adequate resistance to cracking/fracture under the simultaneous actions of corrosion and mechanical stresses, i.e., stress corrosion cracking (SCC) and/or corrosion fatigue (CF). This study investigates the deformation behaviour of a newly developed high-strength low-alloy Mg alloy, MgZn1Ca0.3 (ZX10), processed at two different extrusion temperatures of 325 and 400 °C (named E325 and E400, respectively), under slow strain tensile and cyclic tension-compression loadings in air and modified simulated body fluid (m-SBF). Extrusion resulted in a bimodal grain size distribution with recrystallised grain sizes of 1.2 μm ± 0.8 μm and 7 ± 5 μm for E325 and E400, respectively. E325 possessed superior tensile and fatigue properties to E400 when tested in air. This is mainly attributed to a grain-boundary strengthening mechanism. However, both E325 and E400 were found to be susceptible to SCC at a strain rate of 3.1×10−7 s−1 in m-SBF. Moreover, both E325 and E400 showed similar fatigue strength when tested in m-SBF. This is explained on the basis of crack initiation from localised corrosion following tests in m-SBF.

Original languageEnglish
Pages (from-to)634-643
Number of pages10
JournalJournal of the Mechanical Behavior of Biomedical Materials
Volume65
DOIs
Publication statusPublished - 1 Jan 2017

Keywords

  • Biodegradable implants
  • Corrosion fatigue
  • Magnesium alloys
  • Stress corrosion cracking
  • Twinning

Cite this

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title = "Stress corrosion cracking and corrosion fatigue characterisation of MgZn1Ca0.3 (ZX10) in a simulated physiological environment",
abstract = "Magnesium (Mg) alloys have attracted great attention as potential materials for biodegradable implants. It is essential that an implant material possesses adequate resistance to cracking/fracture under the simultaneous actions of corrosion and mechanical stresses, i.e., stress corrosion cracking (SCC) and/or corrosion fatigue (CF). This study investigates the deformation behaviour of a newly developed high-strength low-alloy Mg alloy, MgZn1Ca0.3 (ZX10), processed at two different extrusion temperatures of 325 and 400 °C (named E325 and E400, respectively), under slow strain tensile and cyclic tension-compression loadings in air and modified simulated body fluid (m-SBF). Extrusion resulted in a bimodal grain size distribution with recrystallised grain sizes of 1.2 μm ± 0.8 μm and 7 ± 5 μm for E325 and E400, respectively. E325 possessed superior tensile and fatigue properties to E400 when tested in air. This is mainly attributed to a grain-boundary strengthening mechanism. However, both E325 and E400 were found to be susceptible to SCC at a strain rate of 3.1×10−7 s−1 in m-SBF. Moreover, both E325 and E400 showed similar fatigue strength when tested in m-SBF. This is explained on the basis of crack initiation from localised corrosion following tests in m-SBF.",
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Stress corrosion cracking and corrosion fatigue characterisation of MgZn1Ca0.3 (ZX10) in a simulated physiological environment. / Jafari, Sajjad; Raman, R. K. Singh; Davies, Chris H.J.; Hofstetter, Joelle; Uggowitzer, Peter J; Löffler, Jörg F.

In: Journal of the Mechanical Behavior of Biomedical Materials, Vol. 65, 01.01.2017, p. 634-643.

Research output: Contribution to journalArticleResearchpeer-review

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T1 - Stress corrosion cracking and corrosion fatigue characterisation of MgZn1Ca0.3 (ZX10) in a simulated physiological environment

AU - Jafari, Sajjad

AU - Raman, R. K. Singh

AU - Davies, Chris H.J.

AU - Hofstetter, Joelle

AU - Uggowitzer, Peter J

AU - Löffler, Jörg F.

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