Stimuli-triggered off/on switchable complexation between a novel type of charge-generation polymer (CGP) and gold nanoparticles for the sensitive colorimetric detection of hydrogen peroxide and glucose

Changhua Li, Jinming Hu, Tao Liu, Shiyong Liu

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79 Citations (Scopus)

Abstract

An effective strategy for the quantitative and sensitive colorimetric detection of H2O2 and glucose by combining a novel concept of stimuli-triggered charge-generation polymer (termed as CGP) with gold nanoparticles (AuNPs) was investigated. A new polymerizable monomer, PBMA, was designed and synthesized, through the reaction of boronate ester-functionalized benzyl alcohol derivative with 2-isocyanatoethyl methacrylate. As PBMA monomer lacks sufficient water solubility, it was opted to synthesize PBMA-containing water-soluble polymers through the free radical copolymerization of PBMA with N, N-dimethylacrylamide (DMA). The obtained P(DMA-co-PBMA) copolymer was subjected to further fractionation to afford relatively narrow-disperse samples. 1H NMR and gel permeation chromatography analysis revealed an overall degree of polymerization (DP) of 620, an Mw/Mn of 1.27, and a PBMA molar content of 11 .
Original languageEnglish
Pages (from-to)429 - 431
Number of pages3
JournalMacromolecules
Volume44
Issue number3
DOIs
Publication statusPublished - 2011
Externally publishedYes

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