Steric control of sorting regimes in self-assembled cages

Samuel E. Walker; Stephanie A. Boer; Thomas Malcomson; Martin J. Paterson; Kellie L. Tuck; David R. Turner

doi:10.1039/d1cc05610g

Steric control of sorting regimes in self-assembled cages

Samuel E. Walker, Stephanie A. Boer, Thomas Malcomson, Martin J. Paterson, Kellie L. Tuck, David R. Turner

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

22 Citations (Scopus)

Abstract

Control of self-sorting regimes is achieved through adjustment of steric interactions in self-assembled coordination cages. The self-assembly regime of dynamic mixtures of heteroleptic cages is followed by HPLC to show that statistical or biased distributions can be selectively obtained, including isolation of a single heteroleptic species.

Original language	English
Pages (from-to)	12456-12459
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	93
DOIs	https://doi.org/10.1039/d1cc05610g
Publication status	Published - 4 Dec 2021

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10.1039/d1cc05610g

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title = "Steric control of sorting regimes in self-assembled cages",

abstract = "Control of self-sorting regimes is achieved through adjustment of steric interactions in self-assembled coordination cages. The self-assembly regime of dynamic mixtures of heteroleptic cages is followed by HPLC to show that statistical or biased distributions can be selectively obtained, including isolation of a single heteroleptic species.",

author = "Walker, \{Samuel E.\} and Boer, \{Stephanie A.\} and Thomas Malcomson and Paterson, \{Martin J.\} and Tuck, \{Kellie L.\} and Turner, \{David R.\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2021",

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doi = "10.1039/d1cc05610g",

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T1 - Steric control of sorting regimes in self-assembled cages

AU - Walker, Samuel E.

AU - Boer, Stephanie A.

AU - Malcomson, Thomas

AU - Paterson, Martin J.

AU - Tuck, Kellie L.

AU - Turner, David R.

PY - 2021/12/4

Y1 - 2021/12/4

N2 - Control of self-sorting regimes is achieved through adjustment of steric interactions in self-assembled coordination cages. The self-assembly regime of dynamic mixtures of heteroleptic cages is followed by HPLC to show that statistical or biased distributions can be selectively obtained, including isolation of a single heteroleptic species.

AB - Control of self-sorting regimes is achieved through adjustment of steric interactions in self-assembled coordination cages. The self-assembly regime of dynamic mixtures of heteroleptic cages is followed by HPLC to show that statistical or biased distributions can be selectively obtained, including isolation of a single heteroleptic species.

UR - https://www.scopus.com/pages/publications/85120362351

U2 - 10.1039/d1cc05610g

DO - 10.1039/d1cc05610g

M3 - Article

AN - SCOPUS:85120362351

SN - 1359-7345

VL - 57

SP - 12456

EP - 12459

JO - Chemical Communications

JF - Chemical Communications

IS - 93

ER -

Steric control of sorting regimes in self-assembled cages

Abstract

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Australian Synchrotron

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Steric control of sorting regimes in self-assembled cages

Abstract

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Australian Synchrotron

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