Stereoselective synthesis of trans-α-ketohydrazones from silyl enol ethers mediated by iodobenzene diacetate

Weidong Rao; Philip Wai Hong Chan

doi:10.1016/j.tetlet.2007.03.164

Stereoselective synthesis of trans-α-ketohydrazones from silyl enol ethers mediated by iodobenzene diacetate

Weidong Rao, Philip Wai Hong Chan

Research output: Contribution to journal › Article › Research › peer-review

10 Citations (Scopus)

Abstract

Stereoselective synthesis of a variety of trans-α-ketohydrazones from silyl enol ethers in the presence of iodobenzene diacetate [PhI(OAc)₂] as oxidant with N-aminophthalimide (PthNH₂) as the nitrogen source in CH₂Cl₂ at room temperature was accomplished in good yields (up to 75%) with exclusive trans-selectivity.

Original language	English
Pages (from-to)	3789-3792
Number of pages	4
Journal	Tetrahedron Letters
Volume	48
Issue number	22
DOIs	https://doi.org/10.1016/j.tetlet.2007.03.164
Publication status	Published - 28 May 2007
Externally published	Yes

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10.1016/j.tetlet.2007.03.164

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title = "Stereoselective synthesis of trans-α-ketohydrazones from silyl enol ethers mediated by iodobenzene diacetate",

abstract = "Stereoselective synthesis of a variety of trans-α-ketohydrazones from silyl enol ethers in the presence of iodobenzene diacetate [PhI(OAc)2] as oxidant with N-aminophthalimide (PthNH2) as the nitrogen source in CH2Cl2 at room temperature was accomplished in good yields (up to 75%) with exclusive trans-selectivity.",

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AU - Chan, Philip Wai Hong

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AB - Stereoselective synthesis of a variety of trans-α-ketohydrazones from silyl enol ethers in the presence of iodobenzene diacetate [PhI(OAc)2] as oxidant with N-aminophthalimide (PthNH2) as the nitrogen source in CH2Cl2 at room temperature was accomplished in good yields (up to 75%) with exclusive trans-selectivity.

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JO - Tetrahedron Letters

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ER -

Stereoselective synthesis of trans-α-ketohydrazones from silyl enol ethers mediated by iodobenzene diacetate

Abstract

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